The present communication describes the identification and structural characterization of a photo-induced transient trinuclear Ag-Pt-Pt complex, in which a pronounced internal structural change of the excited-state PtPOP moiety is observed upon complexation with the Ag ion.
Centre for Molecular Movies, Department of Chemistry and Niels Bohr Institute, University of Copenhagen, Universtitesparken 5, DK-2100 Copenhagen, Denmark.