| pubmed-article:20189186 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:20189186 | lifeskim:mentions | umls-concept:C0020056 | lld:lifeskim |
| pubmed-article:20189186 | lifeskim:mentions | umls-concept:C0040302 | lld:lifeskim |
| pubmed-article:20189186 | lifeskim:mentions | umls-concept:C0032521 | lld:lifeskim |
| pubmed-article:20189186 | lifeskim:mentions | umls-concept:C1328819 | lld:lifeskim |
| pubmed-article:20189186 | lifeskim:mentions | umls-concept:C2717789 | lld:lifeskim |
| pubmed-article:20189186 | pubmed:issue | 14 | lld:pubmed |
| pubmed-article:20189186 | pubmed:dateCreated | 2010-3-15 | lld:pubmed |
| pubmed-article:20189186 | pubmed:abstractText | A new method for the fixation of polymethacrylate monoliths within titanium tubing of up to 0.8 mm I.D. for use as a chromatographic column under elevated temperatures and pressures is described. The preparation of butyl methacrylate-ethylene dimethacrylate-based monolithic stationary phases with desired porous structures was achieved within titanium tubing with pre-oxidised internal walls. The oxidised titanium surface was subsequently silanised with 3-trimethoxysilylpropyl methacrylate resulting in tight bonding of butyl methacrylate porous monolith to the internal walls, providing stationary phase stability at column temperatures up to 110 degrees C and at operating column pressure drops of >28 MPa. The titanium housed monoliths exhibited a uniform and dense porous structure, which provided peak efficiencies of up to 59,000 theoretical plates per meter when evaluated for the separation of small molecules in reversed-phase mode, under optimal conditions (achieved at 15 microL/min and temperature of 110 degrees C for naphthalene with a retention factor, k=0.58). The developed column was applied to the reversed-phase isocratic separation of a text mixture of pesticides. | lld:pubmed |
| pubmed-article:20189186 | pubmed:language | eng | lld:pubmed |
| pubmed-article:20189186 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20189186 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:20189186 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20189186 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20189186 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20189186 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20189186 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20189186 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20189186 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20189186 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20189186 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:20189186 | pubmed:month | Apr | lld:pubmed |
| pubmed-article:20189186 | pubmed:issn | 1873-3778 | lld:pubmed |
| pubmed-article:20189186 | pubmed:author | pubmed-author:PaullBrettB | lld:pubmed |
| pubmed-article:20189186 | pubmed:author | pubmed-author:ConnollyDamia... | lld:pubmed |
| pubmed-article:20189186 | pubmed:author | pubmed-author:NesterenkoPav... | lld:pubmed |
| pubmed-article:20189186 | pubmed:author | pubmed-author:NesterenkoEka... | lld:pubmed |
| pubmed-article:20189186 | pubmed:author | pubmed-author:LacroixFlavie... | lld:pubmed |
| pubmed-article:20189186 | pubmed:copyrightInfo | Copyright (c) 2010 Elsevier B.V. All rights reserved. | lld:pubmed |
| pubmed-article:20189186 | pubmed:issnType | Electronic | lld:pubmed |
| pubmed-article:20189186 | pubmed:day | 2 | lld:pubmed |
| pubmed-article:20189186 | pubmed:volume | 1217 | lld:pubmed |
| pubmed-article:20189186 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:20189186 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:20189186 | pubmed:pagination | 2138-46 | lld:pubmed |
| pubmed-article:20189186 | pubmed:meshHeading | pubmed-meshheading:20189186... | lld:pubmed |
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| pubmed-article:20189186 | pubmed:meshHeading | pubmed-meshheading:20189186... | lld:pubmed |
| pubmed-article:20189186 | pubmed:year | 2010 | lld:pubmed |
| pubmed-article:20189186 | pubmed:articleTitle | Micro-bore titanium housed polymer monoliths for reversed-phase liquid chromatography of small molecules. | lld:pubmed |
| pubmed-article:20189186 | pubmed:affiliation | Irish Separation Science Cluster, National Centre for Sensor Research, Dublin City University, Glasnevin, Dublin 9, Ireland. | lld:pubmed |
| pubmed-article:20189186 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:20189186 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
