pubmed-article:19544512 | rdf:type | pubmed:Citation | lld:pubmed |
pubmed-article:19544512 | pubmed:issue | 29 | lld:pubmed |
pubmed-article:19544512 | pubmed:dateCreated | 2009-7-20 | lld:pubmed |
pubmed-article:19544512 | pubmed:abstractText | The self-organization of multicomponent supramolecular systems involving a variety of two-dimensional (2 D) polygons and three-dimensional (3 D) cages is presented. Nine self-organizing systems, SS(1)-SS(9), have been studied. Each involves the simultaneous mixing of organoplatinum acceptors and pyridyl donors of varying geometry and their selective self-assembly into three to four specific 2 D (rectangular, triangular, and rhomboid) and/or 3 D (triangular prism and distorted and nondistorted trigonal bipyramidal) supramolecules. The formation of these discrete structures is characterized using NMR spectroscopy and electrospray ionization mass spectrometry (ESI-MS). In all cases, the self-organization process is directed by: 1) the geometric information encoded within the molecular subunits and 2) a thermodynamically driven dynamic self-correction process. The result is the selective self-assembly of multiple discrete products from a randomly formed complex. The influence of key experimental variables--temperature and solvent--on the self-correction process and the fidelity of the resulting self-organization systems is also described. | lld:pubmed |
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pubmed-article:19544512 | pubmed:language | eng | lld:pubmed |
pubmed-article:19544512 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19544512 | pubmed:citationSubset | IM | lld:pubmed |
pubmed-article:19544512 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19544512 | pubmed:status | MEDLINE | lld:pubmed |
pubmed-article:19544512 | pubmed:month | Jul | lld:pubmed |
pubmed-article:19544512 | pubmed:issn | 1521-3765 | lld:pubmed |
pubmed-article:19544512 | pubmed:author | pubmed-author:StangPeter... | lld:pubmed |
pubmed-article:19544512 | pubmed:author | pubmed-author:ZhaoLiangL | lld:pubmed |
pubmed-article:19544512 | pubmed:author | pubmed-author:YangHai-BoHB | lld:pubmed |
pubmed-article:19544512 | pubmed:author | pubmed-author:GhoshKoushikK | lld:pubmed |
pubmed-article:19544512 | pubmed:author | pubmed-author:ZhengYao-Rong... | lld:pubmed |
pubmed-article:19544512 | pubmed:issnType | Electronic | lld:pubmed |
pubmed-article:19544512 | pubmed:day | 20 | lld:pubmed |
pubmed-article:19544512 | pubmed:volume | 15 | lld:pubmed |
pubmed-article:19544512 | pubmed:owner | NLM | lld:pubmed |
pubmed-article:19544512 | pubmed:authorsComplete | Y | lld:pubmed |
pubmed-article:19544512 | pubmed:pagination | 7203-14 | lld:pubmed |
pubmed-article:19544512 | pubmed:dateRevised | 2011-9-26 | lld:pubmed |
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pubmed-article:19544512 | pubmed:year | 2009 | lld:pubmed |
pubmed-article:19544512 | pubmed:articleTitle | Multicomponent supramolecular systems: self-organization in coordination-driven self-assembly. | lld:pubmed |
pubmed-article:19544512 | pubmed:affiliation | Department of Chemistry, University of Utah, 315 South 1400 East, RM, 2020, Salt Lake City, Utah, 84112, USA. | lld:pubmed |
pubmed-article:19544512 | pubmed:publicationType | Journal Article | lld:pubmed |
pubmed-article:19544512 | pubmed:publicationType | Research Support, N.I.H., Extramural | lld:pubmed |