pubmed-article:18177048 | rdf:type | pubmed:Citation | lld:pubmed |
pubmed-article:18177048 | lifeskim:mentions | umls-concept:C0002068 | lld:lifeskim |
pubmed-article:18177048 | lifeskim:mentions | umls-concept:C0443286 | lld:lifeskim |
pubmed-article:18177048 | lifeskim:mentions | umls-concept:C0205217 | lld:lifeskim |
pubmed-article:18177048 | lifeskim:mentions | umls-concept:C0013682 | lld:lifeskim |
pubmed-article:18177048 | pubmed:issue | 3 | lld:pubmed |
pubmed-article:18177048 | pubmed:dateCreated | 2008-1-28 | lld:pubmed |
pubmed-article:18177048 | pubmed:abstractText | Efficiency in olefin cross-metathesis reactions is affected upon reducing the steric bulk of N-heterocyclic carbene ligands of ruthenium-based catalysts. For the formation of disubstituted olefins containing one or more allylic substituents, the catalyst bearing N-tolyl groups is more efficient than the corresponding N-mesityl catalyst. In contrast, the formation of trisubstituted olefins is more efficient using the N-mesityl-containing catalyst. A hypothesis to explain this dichotomy is described. | lld:pubmed |
pubmed-article:18177048 | pubmed:grant | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:18177048 | pubmed:language | eng | lld:pubmed |
pubmed-article:18177048 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:18177048 | pubmed:citationSubset | IM | lld:pubmed |
pubmed-article:18177048 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:18177048 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:18177048 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:18177048 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:18177048 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:18177048 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:18177048 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:18177048 | pubmed:status | MEDLINE | lld:pubmed |
pubmed-article:18177048 | pubmed:month | Feb | lld:pubmed |
pubmed-article:18177048 | pubmed:issn | 1523-7060 | lld:pubmed |
pubmed-article:18177048 | pubmed:author | pubmed-author:GrubbsRobert... | lld:pubmed |
pubmed-article:18177048 | pubmed:author | pubmed-author:DouglasChrist... | lld:pubmed |
pubmed-article:18177048 | pubmed:author | pubmed-author:StewartIan... | lld:pubmed |
pubmed-article:18177048 | pubmed:issnType | Print | lld:pubmed |
pubmed-article:18177048 | pubmed:day | 7 | lld:pubmed |
pubmed-article:18177048 | pubmed:volume | 10 | lld:pubmed |
pubmed-article:18177048 | pubmed:owner | NLM | lld:pubmed |
pubmed-article:18177048 | pubmed:authorsComplete | Y | lld:pubmed |
pubmed-article:18177048 | pubmed:pagination | 441-4 | lld:pubmed |
pubmed-article:18177048 | pubmed:meshHeading | pubmed-meshheading:18177048... | lld:pubmed |
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pubmed-article:18177048 | pubmed:meshHeading | pubmed-meshheading:18177048... | lld:pubmed |
pubmed-article:18177048 | pubmed:year | 2008 | lld:pubmed |
pubmed-article:18177048 | pubmed:articleTitle | Increased efficiency in cross-metathesis reactions of sterically hindered olefins. | lld:pubmed |
pubmed-article:18177048 | pubmed:affiliation | The Arnold and Mabel Beckman Laboratory of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA. | lld:pubmed |
pubmed-article:18177048 | pubmed:publicationType | Journal Article | lld:pubmed |
pubmed-article:18177048 | pubmed:publicationType | Research Support, N.I.H., Extramural | lld:pubmed |
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