Adiabatic ionization potential (9.3411 +/- 0.0008 eV) and cationic vibrational structure of the jet-cooled RNA-base uracil are both accurately and precisely determined for the first time using a vacuum-ultraviolet mass-analyzed threshold ionization spectroscopy.
Department of Chemistry and School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 305-701, Republic of Korea.