| pubmed-article:14769880 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:14769880 | lifeskim:mentions | umls-concept:C0038836 | lld:lifeskim |
| pubmed-article:14769880 | lifeskim:mentions | umls-concept:C1522492 | lld:lifeskim |
| pubmed-article:14769880 | lifeskim:mentions | umls-concept:C1510824 | lld:lifeskim |
| pubmed-article:14769880 | lifeskim:mentions | umls-concept:C0348080 | lld:lifeskim |
| pubmed-article:14769880 | lifeskim:mentions | umls-concept:C0065015 | lld:lifeskim |
| pubmed-article:14769880 | lifeskim:mentions | umls-concept:C2346592 | lld:lifeskim |
| pubmed-article:14769880 | pubmed:issue | 6 | lld:pubmed |
| pubmed-article:14769880 | pubmed:dateCreated | 2004-2-10 | lld:pubmed |
| pubmed-article:14769880 | pubmed:abstractText | We studied the mechanism of formation of oxygen radicals during ferrous ion-induced decomposition of linoleic acid hydroperoxide using the spin trapping and chemiluminescence methods. The formation of the superoxide anion (O2*-) was verified in the present study. The hydroxyl radical is also generated through Fenton type decomposition of hydrogen peroxide produced on disproportionation of O2*-. A carbon-centered radical was detected using 5-(diethoxyphosphoryl)-5-methyl-1-pyrroline N-oxide (DEPMPO) as a spin trap. Alkoxyl radical formation is essential for the conversion of linoleic acid hydroperoxide into the peroxyl radical by ferrous ion. It is likely that the alkoxyl radical [R1CH(O*)R2] is converted into the hydroxylcarbon radical [R1C*(OH)R2] in water, and that this carbon radical reacts with oxygen to give the alpha-hydroxyperoxyl radical [R1R2C(OH)OO*], which decomposes into the carbocation [R1C+(OH)R2] and O2*-. | lld:pubmed |
| pubmed-article:14769880 | pubmed:language | eng | lld:pubmed |
| pubmed-article:14769880 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:14769880 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:14769880 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:14769880 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:14769880 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:14769880 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:14769880 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:14769880 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:14769880 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:14769880 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:14769880 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:14769880 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:14769880 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:14769880 | pubmed:month | Dec | lld:pubmed |
| pubmed-article:14769880 | pubmed:issn | 0021-924X | lld:pubmed |
| pubmed-article:14769880 | pubmed:author | pubmed-author:YagiKunioK | lld:pubmed |
| pubmed-article:14769880 | pubmed:author | pubmed-author:KatoMasashiM | lld:pubmed |
| pubmed-article:14769880 | pubmed:author | pubmed-author:NakanoMinoruM | lld:pubmed |
| pubmed-article:14769880 | pubmed:author | pubmed-author:OginoKeikiK | lld:pubmed |
| pubmed-article:14769880 | pubmed:author | pubmed-author:Tero-KubotaSh... | lld:pubmed |
| pubmed-article:14769880 | pubmed:author | pubmed-author:YamamotoYorih... | lld:pubmed |
| pubmed-article:14769880 | pubmed:author | pubmed-author:KambayashiYas... | lld:pubmed |
| pubmed-article:14769880 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:14769880 | pubmed:volume | 134 | lld:pubmed |
| pubmed-article:14769880 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:14769880 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:14769880 | pubmed:pagination | 903-9 | lld:pubmed |
| pubmed-article:14769880 | pubmed:dateRevised | 2011-11-17 | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:meshHeading | pubmed-meshheading:14769880... | lld:pubmed |
| pubmed-article:14769880 | pubmed:year | 2003 | lld:pubmed |
| pubmed-article:14769880 | pubmed:articleTitle | Formation of superoxide anion during ferrous ion-induced decomposition of linoleic acid hydroperoxide under aerobic conditions. | lld:pubmed |
| pubmed-article:14769880 | pubmed:affiliation | Department of Photon and Free Radical Research, Japan Immunoresearch Laboratories, 351-1 Nishiyokote-cho, Takasaki 370-0021. kambayashi@pub.m.kanazawa-u.ac.jp | lld:pubmed |
| pubmed-article:14769880 | pubmed:publicationType | Journal Article | lld:pubmed |
