| pubmed-article:12932473 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:12932473 | lifeskim:mentions | umls-concept:C0036576 | lld:lifeskim |
| pubmed-article:12932473 | lifeskim:mentions | umls-concept:C0024485 | lld:lifeskim |
| pubmed-article:12932473 | pubmed:issue | 1 | lld:pubmed |
| pubmed-article:12932473 | pubmed:dateCreated | 2003-8-22 | lld:pubmed |
| pubmed-article:12932473 | pubmed:abstractText | Spin-state selection in solid-state NMR is demonstrated, using similar pulse sequences as used in liquid-state NMR. The different transitions of all three carbon resonances in fully 13C-labeled L-alanine are separated in different spectra. By selecting spin-states, the contribution of the J-coupling to the linewidth is removed, leading to a considerable enhancement in resolution. The spin-state-selective technique is demonstrated for magic-angle spinning frequencies from 6 to 35kHz. Other experimental conditions affecting the sensitivity of the experiments are discussed. Sensitivity losses due to the introduction of the spin-state-selective filter are shown to be acceptable. Finally, spin-state selection was used to experimentally confirm the differential broadening expected for the two transitions of the CH3 resonance. | lld:pubmed |
| pubmed-article:12932473 | pubmed:language | eng | lld:pubmed |
| pubmed-article:12932473 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12932473 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:12932473 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12932473 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12932473 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12932473 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:12932473 | pubmed:month | Sep | lld:pubmed |
| pubmed-article:12932473 | pubmed:issn | 1090-7807 | lld:pubmed |
| pubmed-article:12932473 | pubmed:author | pubmed-author:EmsleyLyndonL | lld:pubmed |
| pubmed-article:12932473 | pubmed:author | pubmed-author:LesageAnneA | lld:pubmed |
| pubmed-article:12932473 | pubmed:author | pubmed-author:HedigerSabine... | lld:pubmed |
| pubmed-article:12932473 | pubmed:author | pubmed-author:DumaLuminitaL | lld:pubmed |
| pubmed-article:12932473 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:12932473 | pubmed:volume | 164 | lld:pubmed |
| pubmed-article:12932473 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:12932473 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:12932473 | pubmed:pagination | 187-95 | lld:pubmed |
| pubmed-article:12932473 | pubmed:meshHeading | pubmed-meshheading:12932473... | lld:pubmed |
| pubmed-article:12932473 | pubmed:meshHeading | pubmed-meshheading:12932473... | lld:pubmed |
| pubmed-article:12932473 | pubmed:meshHeading | pubmed-meshheading:12932473... | lld:pubmed |
| pubmed-article:12932473 | pubmed:meshHeading | pubmed-meshheading:12932473... | lld:pubmed |
| pubmed-article:12932473 | pubmed:meshHeading | pubmed-meshheading:12932473... | lld:pubmed |
| pubmed-article:12932473 | pubmed:meshHeading | pubmed-meshheading:12932473... | lld:pubmed |
| pubmed-article:12932473 | pubmed:meshHeading | pubmed-meshheading:12932473... | lld:pubmed |
| pubmed-article:12932473 | pubmed:year | 2003 | lld:pubmed |
| pubmed-article:12932473 | pubmed:articleTitle | Spin-state selection in solid-state NMR. | lld:pubmed |
| pubmed-article:12932473 | pubmed:affiliation | Laboratoire de Chimie (UMR-5532 CNRS/ENS), Laboratoire de Recherche Conventionné du CEA (23V), Ecole Normale Supérieure de Lyon, 46 Allée d'Italie, 69364 Lyon, France. | lld:pubmed |
| pubmed-article:12932473 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:12932473 | pubmed:publicationType | Evaluation Studies | lld:pubmed |
| pubmed-article:12932473 | pubmed:publicationType | Validation Studies | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:12932473 | lld:pubmed |
