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12099867

Source:http://linkedlifedata.com/resource/pubmed/id/12099867

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pubmed-article:12099867pubmed:issue14lld:pubmed
pubmed-article:12099867pubmed:dateCreated2002-7-8lld:pubmed
pubmed-article:12099867pubmed:abstractTextWe have studied an anionic ligand effect in iron porphyrin complex-catalyzed competitive epoxidations of cis- and trans-stilbenes by various terminal oxidants and found that the ratios of cis- to trans-stilbene oxide products formed in competitive epoxidations were markedly dependent on the ligating nature of the anionic ligands. The ratios of cis- to trans-stilbene oxides obtained in the reactions of Fe(TPP)X (TPP = meso-tetraphenylporphinato dianion and X(-) = anionic ligand) and iodosylbenzene (PhIO) were 14 and 0.9 when the X(-) of Fe(TPP)X was Cl(-) and CF(3)SO(3)(-), respectively. An anionic ligand effect was also observed in the reactions of an electron-deficient iron(III) porphyrin complex containing a number of different anionic ligands, Fe(TPFPP)X [TPFPP = meso-tetrakis(pentafluorophenyl)porphinato dianion and X(-) = anionic ligand], and various terminal oxidants such as PhIO, m-chloroperoxybenzoic acid (m-CPBA), tetrabutylammonium oxone (TBAO), and H(2)O(2). While high ratios of cis- to trans-stilbene oxides were obtained in the reactions of iron porphyrin catalysts containing ligating anionic ligands such as Cl(-) and OAc(-), the ratios of cis- to trans-stilbene oxide were low in the reactions of iron porphyrin complexes containing nonligating or weakly ligating anionic ligands such as SbF(6)(-), CF(3)SO(3)(-), and ClO(4)(-). When the anionic ligand was NO(3)(-), the product ratios were found to depend on terminal oxidants and olefin concentrations. We suggest that the dependence of the product ratios on the anionic ligands of iron(III) porphyrin catalysts is due to the involvement of different reactive species in olefin epoxidation reactions. That is, high-valent iron(IV) oxo porphyrin cation radicals are generated as a reactive species in the reactions of iron porphyrin catalysts containing nonligating or weakly ligating anionic ligands such as SbF(6)(-), CF(3)SO(3)(-), and ClO(4)(-), whereas oxidant-iron(III) porphyrin complexes are the reactive intermediates in the reactions of iron porphyrin catalysts containing ligating anionic ligands such as Cl(-) and OAc(-).lld:pubmed
pubmed-article:12099867pubmed:languageenglld:pubmed
pubmed-article:12099867pubmed:journalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:12099867pubmed:statusPubMed-not-MEDLINElld:pubmed
pubmed-article:12099867pubmed:monthJullld:pubmed
pubmed-article:12099867pubmed:issn0020-1669lld:pubmed
pubmed-article:12099867pubmed:authorpubmed-author:NamWonwooWlld:pubmed
pubmed-article:12099867pubmed:authorpubmed-author:LimMi HeeMHlld:pubmed
pubmed-article:12099867pubmed:authorpubmed-author:JinSook WonSWlld:pubmed
pubmed-article:12099867pubmed:authorpubmed-author:RyuJu YeonJYlld:pubmed
pubmed-article:12099867pubmed:authorpubmed-author:KimChealClld:pubmed
pubmed-article:12099867pubmed:issnTypePrintlld:pubmed
pubmed-article:12099867pubmed:day15lld:pubmed
pubmed-article:12099867pubmed:volume41lld:pubmed
pubmed-article:12099867pubmed:ownerNLMlld:pubmed
pubmed-article:12099867pubmed:authorsCompleteYlld:pubmed
pubmed-article:12099867pubmed:pagination3647-52lld:pubmed
pubmed-article:12099867pubmed:dateRevised2003-11-3lld:pubmed
pubmed-article:12099867pubmed:year2002lld:pubmed
pubmed-article:12099867pubmed:articleTitleAnionic ligand effect on the nature of epoxidizing intermediates in iron porphyrin complex-catalyzed epoxidation reactions.lld:pubmed
pubmed-article:12099867pubmed:affiliationDepartment of Chemistry and Division of Molecular Life Sciences, Ewha Womans University, Seoul 120-750, Korea. wwnam@ewha.ac.krlld:pubmed
pubmed-article:12099867pubmed:publicationTypeJournal Articlelld:pubmed
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