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pubmed-article:11428027pubmed:abstractText[figure: see text] Thermolysis of lactone 18 initiated a stereospecific transannular nitrone-olefin [3 + 2] cycloaddition to yield tetracycle 19. Methanolysis followed by reductive cleavage of the isoxazolidine yielded 20, representing the azaspirocyclic core of pinnaic acid (1).lld:pubmed
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pubmed-article:11428027pubmed:articleTitleTransannular nitrone cycloaddition. A stereocontrolled entry to the spirocyclic core of pinnaic acid.lld:pubmed
pubmed-article:11428027pubmed:affiliationDepartment of Chemistry, Oregon State University, Corvallis, Oregon 97331-4003, USA. james.white@orst.edulld:pubmed
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