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pubmed-article:10993362pubmed:abstractTextThe "one-pot" synthesis of triarylamines from an aniline and two different aryl halides is described. A catalytic system composed of Pd2(dba)3/P(t-Bu)2-o-biphenyl (1) is used to prepare a variety of triarylamines in a single flask by the coupling of an aniline with an aryl bromide and aryl chloride. The synthesis of triarylamines containing a heterocyclic aryl group is also described by employing a one-flask, two-step method. These methods can be used to synthesize both discrete triarylamines and a triarylamine library.lld:pubmed
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pubmed-article:10993362pubmed:authorpubmed-author:HarrisM CMClld:pubmed
pubmed-article:10993362pubmed:authorpubmed-author:BuchwaldS LSLlld:pubmed
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pubmed-article:10993362pubmed:pagination5327-33lld:pubmed
pubmed-article:10993362pubmed:dateRevised2007-11-14lld:pubmed
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pubmed-article:10993362pubmed:articleTitleOne-pot synthesis of unsymmetrical triarylamines from aniline precursors.lld:pubmed
pubmed-article:10993362pubmed:affiliationDepartment of Chemistry, Massachusetts Institute of Technology, Cambridge 02139, USA.lld:pubmed
pubmed-article:10993362pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:10993362pubmed:publicationTypeResearch Support, U.S. Gov't, P.H.S.lld:pubmed
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