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pubmed-article:9125182pubmed:abstractTextThe fatty acid alpha-ketol 13-hydroxy-12-oxo-9(Z)-octadecenoic acid (methyl ester) was incubated with a bacterial culture isolated from soil. The bacteria (tentatively identified as Ralstonia sp.) exhibited strong monooxygenase activity growing on 2-tridecanone as sole source of carbon. They catalyzed a Baeyer-Villiger type of oxidation and converted the alpha-ketol to 3(Z)-dodecendioic acid. 3(Z)-Dodecendioic acid was isolated from the incubation mixture and identified by comparison with an authentic reference compound. These findings offer both a physiological role for alpha-ketol fatty acids in plant lipid hydroperoxide metabolism and new insights into an alternative biosynthetic pathway leading to traumatic acid (2(E)-dodecendioic acid).lld:pubmed
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pubmed-article:9125182pubmed:authorpubmed-author:SchneiderCClld:pubmed
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pubmed-article:9125182pubmed:pagination364-6lld:pubmed
pubmed-article:9125182pubmed:dateRevised2006-11-15lld:pubmed
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pubmed-article:9125182pubmed:articleTitleA fatty acid alpha-ketol, a product of the plant lipoxygenase pathway, is oxidized to 3(Z)-dodecendioic acid by a bacterial monooxygenase.lld:pubmed
pubmed-article:9125182pubmed:affiliationLehrstuhl für Lebensmittelchemie, Universität Würzburg, Germany.lld:pubmed
pubmed-article:9125182pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:9125182pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed