| pubmed-article:21808646 | pubmed:abstractText | The mole ratio r(r = [I(-)](0)/[ClO(2)](0)) has great influence on ClO(2)-I(-)-H(2)SO(4) closed reaction system. By changing the initiate concentration of potassium iodide, the curve of absorbance along with the reaction time was obtained at 350?nm and 297?nm for triiodide ion, and 460?nm for iodine. The changing point of the absorbance curve's shape locates at r = 6.00. For the reaction of ClO(2)-I(-) in the absence of H(2)SO(4), the curve of absorbance along with the reaction time can be obtained at 350?nm for triiodide ion, 460?nm for iodine. The mole ratio r is equal to 1.00 is the changing point of the curve's shape no matter at which wavelength to determine the reaction. For the reaction of ClO(2)-I(-)-H(+) in different pH buffer solution, the curve of absorbance along with the reaction time was recorded at 460?nm for iodine. When r is greater than 1.00, the transition point of the curve's shape locates at pH 2.0, which is also the point of producing chlorite or chloride for chlorine dioxide at different pH. When r is less than 1.00, the transition point locates at pH 7.0. | lld:pubmed |
