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pubmed-article:21696752pubmed:abstractTextUsing phase-sensitive streaming potential experiments in a vacuum chamber, we demonstrate that lowering the ambient pressure of the air surrounding a hydrophobic, Zeonor microfluidic substrate results in a decrease in the time scale required for equilibration of the electrokinetic potential. At ambient air pressures below 0.74 atm, the electrokinetic potential changes from ?-84 mV to ?-11 mV in 5 h, while the same decrease occurs in a period of over 200 h when the system is at 1 atm. Returning a sub-atmospheric system (where the electrokinetic potential had equilibrated to -11 mV) to atmospheric pressure did not result in any additional change in the electrokinetic potential. This can be described as a type of hysteresis of the electrokinetic potential with dissolved gas concentration. No time or pressure dependence was observed for the electrokinetic potential of hydrophilic (silica) substrates.lld:pubmed
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pubmed-article:21696752pubmed:issn1095-7103lld:pubmed
pubmed-article:21696752pubmed:authorpubmed-author:KirbyBrian...lld:pubmed
pubmed-article:21696752pubmed:authorpubmed-author:TandonVishalVlld:pubmed
pubmed-article:21696752pubmed:copyrightInfoCopyright © 2011 Elsevier Inc. All rights reserved.lld:pubmed
pubmed-article:21696752pubmed:issnTypeElectroniclld:pubmed
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pubmed-article:21696752pubmed:volume361lld:pubmed
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pubmed-article:21696752pubmed:year2011lld:pubmed
pubmed-article:21696752pubmed:articleTitleAmbient pressure effects on the electrokinetic potential of Zeonor-water interfaces.lld:pubmed
pubmed-article:21696752pubmed:affiliationDepartment of Biomedical Engineering, Cornell University, United States.lld:pubmed
pubmed-article:21696752pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:21696752pubmed:publicationTypeResearch Support, U.S. Gov't, Non-P.H.S.lld:pubmed
pubmed-article:21696752pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed