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pubmed-article:21611650pubmed:issue13lld:pubmed
pubmed-article:21611650pubmed:dateCreated2011-6-15lld:pubmed
pubmed-article:21611650pubmed:abstractTextA new approach for the detection of Hg(2+) is reported based on color changes from which gold nanoparticles (Au NPs) are surrounded by a layer of HgS quantum dots to form in situ Au@HgS core-shell nanostructures. The surface plasmon resonance (SPR) absorption of the gold core was changed due to a shell layer of HgS formed on the surface of the Au NPs, which brings the colour change of the aqueous solution. Therefore, Hg(2+) can be recognized by visualizing the colour change of the Au@HgS core-shell nanostructures, and can be detected quantitatively by measurement of the UV-vis spectra. Some effects on the detection of Hg(2+) were investigated in detail. This method was used to detect Hg(2+) with excellent selectivity and high sensitivity. In our method, the lowest detected concentrations for mercury ions were 5.0 × 10(-6) M observed by the naked eye and 0.486 nM as measured by UV-vis spectra. At the range from 8.0 × 10(-5) to 1.0 × 10(-8) M of Hg(2+), this method was shown to have a good linear relationship.lld:pubmed
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pubmed-article:21611650pubmed:authorpubmed-author:WangHaiyanHlld:pubmed
pubmed-article:21611650pubmed:authorpubmed-author:WuAiguoAlld:pubmed
pubmed-article:21611650pubmed:authorpubmed-author:ZhangFuqiangFlld:pubmed
pubmed-article:21611650pubmed:authorpubmed-author:CuiYangYlld:pubmed
pubmed-article:21611650pubmed:authorpubmed-author:ZengLeyongLlld:pubmed
pubmed-article:21611650pubmed:authorpubmed-author:XinJunweiJlld:pubmed
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pubmed-article:21611650pubmed:volume136lld:pubmed
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pubmed-article:21611650pubmed:pagination2825-30lld:pubmed
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pubmed-article:21611650pubmed:year2011lld:pubmed
pubmed-article:21611650pubmed:articleTitleA one-step colorimetric method of analysis detection of Hg2+ based on an in situ formation of Au@HgS core-shell structures.lld:pubmed
pubmed-article:21611650pubmed:affiliationAnhui Key Laboratory of Chemo-biosensing, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, China.lld:pubmed
pubmed-article:21611650pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:21611650pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed