| pubmed-article:2159336 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:2159336 | lifeskim:mentions | umls-concept:C0205103 | lld:lifeskim |
| pubmed-article:2159336 | lifeskim:mentions | umls-concept:C0010760 | lld:lifeskim |
| pubmed-article:2159336 | lifeskim:mentions | umls-concept:C0030054 | lld:lifeskim |
| pubmed-article:2159336 | lifeskim:mentions | umls-concept:C0443286 | lld:lifeskim |
| pubmed-article:2159336 | lifeskim:mentions | umls-concept:C0205225 | lld:lifeskim |
| pubmed-article:2159336 | pubmed:issue | 6 | lld:pubmed |
| pubmed-article:2159336 | pubmed:dateCreated | 1990-6-14 | lld:pubmed |
| pubmed-article:2159336 | pubmed:abstractText | The reaction of dioxygen with mixed-valence cytochrome c oxidase was followed in a rapid-mixing continuous-flow apparatus. The optical absorption difference spectrum and a kinetic analysis confirm the presence of the primary oxygen intermediate in the 0-100-microseconds time window. The resonance Raman spectrum of the iron-dioxygen stretching mode (568 cm-1) supplies evidence that the degree of electron transfer from the iron atom to the dioxygen is similar to that in oxy complexes of other heme proteins. Thus, the Fe-O2 bond does not display any unique structural features that could account for the rapid reduction of dioxygen to water. Furthermore, the frequency of the iron-dioxygen stretching mode is the same as that of the primary intermediate in the fully reduced enzyme, indicating that the oxidation state of cytochrome a plays no role in controlling the initial properties of the oxygen binding site. | lld:pubmed |
| pubmed-article:2159336 | pubmed:grant | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:2159336 | pubmed:language | eng | lld:pubmed |
| pubmed-article:2159336 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:2159336 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:2159336 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:2159336 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:2159336 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:2159336 | pubmed:month | Feb | lld:pubmed |
| pubmed-article:2159336 | pubmed:issn | 0006-2960 | lld:pubmed |
| pubmed-article:2159336 | pubmed:author | pubmed-author:HamRR | lld:pubmed |
| pubmed-article:2159336 | pubmed:author | pubmed-author:RousseauD LDL | lld:pubmed |
| pubmed-article:2159336 | pubmed:author | pubmed-author:ChingY CYC | lld:pubmed |
| pubmed-article:2159336 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:2159336 | pubmed:day | 13 | lld:pubmed |
| pubmed-article:2159336 | pubmed:volume | 29 | lld:pubmed |
| pubmed-article:2159336 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:2159336 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:2159336 | pubmed:pagination | 1380-4 | lld:pubmed |
| pubmed-article:2159336 | pubmed:dateRevised | 2008-11-21 | lld:pubmed |
| pubmed-article:2159336 | pubmed:meshHeading | pubmed-meshheading:2159336-... | lld:pubmed |
| pubmed-article:2159336 | pubmed:meshHeading | pubmed-meshheading:2159336-... | lld:pubmed |
| pubmed-article:2159336 | pubmed:meshHeading | pubmed-meshheading:2159336-... | lld:pubmed |
| pubmed-article:2159336 | pubmed:meshHeading | pubmed-meshheading:2159336-... | lld:pubmed |
| pubmed-article:2159336 | pubmed:meshHeading | pubmed-meshheading:2159336-... | lld:pubmed |
| pubmed-article:2159336 | pubmed:meshHeading | pubmed-meshheading:2159336-... | lld:pubmed |
| pubmed-article:2159336 | pubmed:meshHeading | pubmed-meshheading:2159336-... | lld:pubmed |
| pubmed-article:2159336 | pubmed:year | 1990 | lld:pubmed |
| pubmed-article:2159336 | pubmed:articleTitle | Primary intermediate in the reaction of mixed-valence cytochrome c oxidase with oxygen. | lld:pubmed |
| pubmed-article:2159336 | pubmed:affiliation | AT&T Bell Laboratories, Murray Hill, New Jersey 07974. | lld:pubmed |
| pubmed-article:2159336 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:2159336 | pubmed:publicationType | Research Support, U.S. Gov't, P.H.S. | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:2159336 | lld:pubmed |
