| pubmed-article:21520953 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:21520953 | lifeskim:mentions | umls-concept:C0444598 | lld:lifeskim |
| pubmed-article:21520953 | lifeskim:mentions | umls-concept:C0023749 | lld:lifeskim |
| pubmed-article:21520953 | lifeskim:mentions | umls-concept:C0009264 | lld:lifeskim |
| pubmed-article:21520953 | lifeskim:mentions | umls-concept:C0039476 | lld:lifeskim |
| pubmed-article:21520953 | lifeskim:mentions | umls-concept:C1257888 | lld:lifeskim |
| pubmed-article:21520953 | lifeskim:mentions | umls-concept:C2603343 | lld:lifeskim |
| pubmed-article:21520953 | lifeskim:mentions | umls-concept:C0206055 | lld:lifeskim |
| pubmed-article:21520953 | pubmed:issue | 19 | lld:pubmed |
| pubmed-article:21520953 | pubmed:dateCreated | 2011-5-12 | lld:pubmed |
| pubmed-article:21520953 | pubmed:abstractText | Temperature-dependent FTIR spectra of linoleic acid were measured over a temperature range of -80 to -30 °C to explore solid-state low-temperature (LT) ? middle-temperature (MT) phase transition of linoleic acid. Band assignments were made mainly for the 900-760 cm(-1) region, where the bands due to cis-olefin group's ?C-H out-of-plane mode and the progression bands due to CH(2) rocking-CH(2) twisting modes are expected to appear. The structural evolutions during the LT ? MT phase transition of linoleic acid were investigated by analyzing the progression bands with the simple-coupled oscillator model to elucidate the features of acyl chain influenced with two cis-C?C bonds linked through one CH(2) group. Structure changes in the LT ? MT transition of linoleic acid were compared with those in the ? ? ? transition of oleic acid. It has been found that the former is rather localized around the cis-diene group, while the latter occurs in the larger portion between the cis-olefin group to the methyl end. It is also suggested that the conformational change in the cis-olefin group on the LT ? MT transition is on a lesser scale than that on the ? ? ? transition. | lld:pubmed |
| pubmed-article:21520953 | pubmed:language | eng | lld:pubmed |
| pubmed-article:21520953 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:21520953 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:21520953 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:21520953 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:21520953 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:21520953 | pubmed:month | May | lld:pubmed |
| pubmed-article:21520953 | pubmed:issn | 1520-5207 | lld:pubmed |
| pubmed-article:21520953 | pubmed:author | pubmed-author:SuzukiMasaoM | lld:pubmed |
| pubmed-article:21520953 | pubmed:author | pubmed-author:OzakiYukihiro... | lld:pubmed |
| pubmed-article:21520953 | pubmed:author | pubmed-author:KanekoFumitos... | lld:pubmed |
| pubmed-article:21520953 | pubmed:author | pubmed-author:IwahashiMakio... | lld:pubmed |
| pubmed-article:21520953 | pubmed:author | pubmed-author:PiFuweiF | lld:pubmed |
| pubmed-article:21520953 | pubmed:copyrightInfo | © 2011 American Chemical Society | lld:pubmed |
| pubmed-article:21520953 | pubmed:issnType | Electronic | lld:pubmed |
| pubmed-article:21520953 | pubmed:day | 19 | lld:pubmed |
| pubmed-article:21520953 | pubmed:volume | 115 | lld:pubmed |
| pubmed-article:21520953 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:21520953 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:21520953 | pubmed:pagination | 6289-95 | lld:pubmed |
| pubmed-article:21520953 | pubmed:meshHeading | pubmed-meshheading:21520953... | lld:pubmed |
| pubmed-article:21520953 | pubmed:meshHeading | pubmed-meshheading:21520953... | lld:pubmed |
| pubmed-article:21520953 | pubmed:meshHeading | pubmed-meshheading:21520953... | lld:pubmed |
| pubmed-article:21520953 | pubmed:meshHeading | pubmed-meshheading:21520953... | lld:pubmed |
| pubmed-article:21520953 | pubmed:meshHeading | pubmed-meshheading:21520953... | lld:pubmed |
| pubmed-article:21520953 | pubmed:meshHeading | pubmed-meshheading:21520953... | lld:pubmed |
| pubmed-article:21520953 | pubmed:year | 2011 | lld:pubmed |
| pubmed-article:21520953 | pubmed:articleTitle | Solid-state low temperature?middle temperature phase transition of linoleic acid studied by FTIR spectroscopy. | lld:pubmed |
| pubmed-article:21520953 | pubmed:affiliation | Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, Sanda, Hyogo 669-1337, Japan. | lld:pubmed |
| pubmed-article:21520953 | pubmed:publicationType | Journal Article | lld:pubmed |
