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pubmed-article:21462964pubmed:abstractTextA diastereoselective synthesis of trans-2-substituted cyclopropanols is outlined. Bimetallic CH(2)(ZnI)(2) was found to react with ?-chloroaldehydes to give cyclopropanols in yields of 64-89% and dr's ? 10:1. The high trans-selectivity resulted from equilibration of the cyclopropoxide intermediates.lld:pubmed
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pubmed-article:21462964pubmed:pagination2346-9lld:pubmed
pubmed-article:21462964pubmed:dateRevised2011-9-26lld:pubmed
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pubmed-article:21462964pubmed:articleTitleDiasteroselective preparation of cyclopropanols using methylene bis(iodozinc).lld:pubmed
pubmed-article:21462964pubmed:affiliationDepartment of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.lld:pubmed
pubmed-article:21462964pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:21462964pubmed:publicationTypeResearch Support, U.S. Gov't, Non-P.H.S.lld:pubmed
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