| pubmed-article:21386563 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:21386563 | lifeskim:mentions | umls-concept:C0205160 | lld:lifeskim |
| pubmed-article:21386563 | lifeskim:mentions | umls-concept:C1705165 | lld:lifeskim |
| pubmed-article:21386563 | lifeskim:mentions | umls-concept:C2700061 | lld:lifeskim |
| pubmed-article:21386563 | pubmed:issue | 40 | lld:pubmed |
| pubmed-article:21386563 | pubmed:dateCreated | 2011-3-9 | lld:pubmed |
| pubmed-article:21386563 | pubmed:abstractText | We investigate the structures of H(3)Co(CN)(6) and D(3)Co(CN)(6) and their temperature dependence using a combination of advanced neutron and x-ray diffraction techniques. Lattice parameter refinements show marked temperature- and isotope-dependent effects in the thermal expansion behaviour. Reverse Monte Carlo modelling of neutron total scattering data characterizes the distribution of D atom positions in the deuterated compound; analysis of these distributions reveals that the two N-H/D bonds become increasingly different with increasing temperature, suggesting a mechanism for the observed thermal expansion anomalies. We discuss these results in the context of the previous crystallographic, spectroscopic and theoretical results for H(3)Co(CN)(6) and 'super-short' N···H···N systems in general. | lld:pubmed |
| pubmed-article:21386563 | pubmed:language | eng | lld:pubmed |
| pubmed-article:21386563 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:21386563 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:21386563 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:21386563 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:21386563 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:21386563 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:21386563 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:21386563 | pubmed:month | Oct | lld:pubmed |
| pubmed-article:21386563 | pubmed:issn | 1361-648X | lld:pubmed |
| pubmed-article:21386563 | pubmed:author | pubmed-author:PetersLarsL | lld:pubmed |
| pubmed-article:21386563 | pubmed:author | pubmed-author:EvansJohn S... | lld:pubmed |
| pubmed-article:21386563 | pubmed:author | pubmed-author:GoodwinAndrew... | lld:pubmed |
| pubmed-article:21386563 | pubmed:author | pubmed-author:TuckerMatthew... | lld:pubmed |
| pubmed-article:21386563 | pubmed:author | pubmed-author:DoveMartin... | lld:pubmed |
| pubmed-article:21386563 | pubmed:author | pubmed-author:KeenDavid ADA | lld:pubmed |
| pubmed-article:21386563 | pubmed:issnType | Electronic | lld:pubmed |
| pubmed-article:21386563 | pubmed:day | 13 | lld:pubmed |
| pubmed-article:21386563 | pubmed:volume | 22 | lld:pubmed |
| pubmed-article:21386563 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:21386563 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:21386563 | pubmed:pagination | 404202 | lld:pubmed |
| pubmed-article:21386563 | pubmed:meshHeading | pubmed-meshheading:21386563... | lld:pubmed |
| pubmed-article:21386563 | pubmed:meshHeading | pubmed-meshheading:21386563... | lld:pubmed |
| pubmed-article:21386563 | pubmed:meshHeading | pubmed-meshheading:21386563... | lld:pubmed |
| pubmed-article:21386563 | pubmed:meshHeading | pubmed-meshheading:21386563... | lld:pubmed |
| pubmed-article:21386563 | pubmed:meshHeading | pubmed-meshheading:21386563... | lld:pubmed |
| pubmed-article:21386563 | pubmed:meshHeading | pubmed-meshheading:21386563... | lld:pubmed |
| pubmed-article:21386563 | pubmed:meshHeading | pubmed-meshheading:21386563... | lld:pubmed |
| pubmed-article:21386563 | pubmed:meshHeading | pubmed-meshheading:21386563... | lld:pubmed |
| pubmed-article:21386563 | pubmed:meshHeading | pubmed-meshheading:21386563... | lld:pubmed |
| pubmed-article:21386563 | pubmed:meshHeading | pubmed-meshheading:21386563... | lld:pubmed |
| pubmed-article:21386563 | pubmed:year | 2010 | lld:pubmed |
| pubmed-article:21386563 | pubmed:articleTitle | The hydrogen-bonding transition and isotope-dependent negative thermal expansion in H3Co(CN)6. | lld:pubmed |
| pubmed-article:21386563 | pubmed:affiliation | ISIS Facility, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX, UK. david.keen@stfc.ac.uk | lld:pubmed |
| pubmed-article:21386563 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:21386563 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
