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pubmed-article:21244036pubmed:dateCreated2011-2-14lld:pubmed
pubmed-article:21244036pubmed:abstractTextSeveral nitrosyl complexes of Fe and Co have been prepared using the sterically hindered Ar-nacnac ligand (Ar-nacnac = anion of [(2,6-diisopropylphenyl)NC(Me)](2)CH). The dinitrosyliron complexes [Fe(NO)(2)(Ar-nacnac)] (1) and (Bu(4)N)[Fe(NO)(2)(Ar-nacnac)] (2) react with [Fe(III)(TPP)Cl] (TPP = tetraphenylporphine dianion) to generate [Fe(II)(NO)(TPP)] and the corresponding mononitrosyliron complexes. The factors governing NO transfer with dinitrosyliron complexes (DNICs) 1 and 2 are evaluated, together with the chemistry of the related mononitrosyliron complex, [Fe(NO)Br(Ar-nacnac)] (4). The synthesis and properties of the related cobalt dinitrosyl [Co(NO)(2)(Ar-nacnac)] (3) is also discussed for comparison to DNICs 1 and 2. The solid-state structures of several of these compounds as determined by X-ray crystallography are reported.lld:pubmed
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pubmed-article:21244036pubmed:authorpubmed-author:DoLoi HLHlld:pubmed
pubmed-article:21244036pubmed:authorpubmed-author:HéroguelFlore...lld:pubmed
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pubmed-article:21244036pubmed:year2011lld:pubmed
pubmed-article:21244036pubmed:articleTitleChemistry of nitrosyliron complexes supported by a ?-diketiminate ligand.lld:pubmed
pubmed-article:21244036pubmed:affiliationDepartment of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.lld:pubmed
pubmed-article:21244036pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:21244036pubmed:publicationTypeResearch Support, U.S. Gov't, Non-P.H.S.lld:pubmed
pubmed-article:21244036pubmed:publicationTypeResearch Support, N.I.H., Extramurallld:pubmed