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pubmed-article:20731395pubmed:abstractTextA series of Cp*Ir complexes can catalyze C-H oxidation, with ceric ammonium nitrate as the terminal oxidant and water as the source of oxygen. Remarkably the hydroxylation of cis-decalin and 1,4-dimethylcyclohexane proceeds with retention of stereochemistry. With H(2)O(18), cis-decalin oxidation gave (18)O incorporation into the product cis-decalol.lld:pubmed
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pubmed-article:20731395pubmed:articleTitleCp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry.lld:pubmed
pubmed-article:20731395pubmed:affiliationChemistry Department, Yale University, P.O. Box 208107, New Haven, Connecticut 06520, USA.lld:pubmed
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