| pubmed-article:20568761 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:20568761 | lifeskim:mentions | umls-concept:C0001992 | lld:lifeskim |
| pubmed-article:20568761 | lifeskim:mentions | umls-concept:C1442750 | lld:lifeskim |
| pubmed-article:20568761 | lifeskim:mentions | umls-concept:C1704259 | lld:lifeskim |
| pubmed-article:20568761 | lifeskim:mentions | umls-concept:C0007382 | lld:lifeskim |
| pubmed-article:20568761 | lifeskim:mentions | umls-concept:C1705987 | lld:lifeskim |
| pubmed-article:20568761 | pubmed:issue | 27 | lld:pubmed |
| pubmed-article:20568761 | pubmed:dateCreated | 2010-7-7 | lld:pubmed |
| pubmed-article:20568761 | pubmed:abstractText | Primary aminothiourea derivatives are shown to catalyze enantioselective alkylation of alpha-arylpriopionaldehdyes with diarylbromomethane. Evidence for a stepwise, S(N)1 mechanism in the substitution reaction induced by anion binding to the catalyst is provided by catalyst structure-activity studies, kinetic isotope effects, linear free-energy relationship studies, and competition experiments. | lld:pubmed |
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| pubmed-article:20568761 | pubmed:language | eng | lld:pubmed |
| pubmed-article:20568761 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20568761 | pubmed:citationSubset | IM | lld:pubmed |
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| pubmed-article:20568761 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:20568761 | pubmed:month | Jul | lld:pubmed |
| pubmed-article:20568761 | pubmed:issn | 1520-5126 | lld:pubmed |
| pubmed-article:20568761 | pubmed:author | pubmed-author:JacobsenEric... | lld:pubmed |
| pubmed-article:20568761 | pubmed:author | pubmed-author:BrownAdam RAR | lld:pubmed |
| pubmed-article:20568761 | pubmed:author | pubmed-author:KuoWen-HsinWH | lld:pubmed |
| pubmed-article:20568761 | pubmed:issnType | Electronic | lld:pubmed |
| pubmed-article:20568761 | pubmed:day | 14 | lld:pubmed |
| pubmed-article:20568761 | pubmed:volume | 132 | lld:pubmed |
| pubmed-article:20568761 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:20568761 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:20568761 | pubmed:pagination | 9286-8 | lld:pubmed |
| pubmed-article:20568761 | pubmed:dateRevised | 2011-8-1 | lld:pubmed |
| pubmed-article:20568761 | pubmed:meshHeading | pubmed-meshheading:20568761... | lld:pubmed |
| pubmed-article:20568761 | pubmed:meshHeading | pubmed-meshheading:20568761... | lld:pubmed |
| pubmed-article:20568761 | pubmed:meshHeading | pubmed-meshheading:20568761... | lld:pubmed |
| pubmed-article:20568761 | pubmed:meshHeading | pubmed-meshheading:20568761... | lld:pubmed |
| pubmed-article:20568761 | pubmed:meshHeading | pubmed-meshheading:20568761... | lld:pubmed |
| pubmed-article:20568761 | pubmed:meshHeading | pubmed-meshheading:20568761... | lld:pubmed |
| pubmed-article:20568761 | pubmed:year | 2010 | lld:pubmed |
| pubmed-article:20568761 | pubmed:articleTitle | Enantioselective catalytic alpha-alkylation of aldehydes via an SN1 pathway. | lld:pubmed |
| pubmed-article:20568761 | pubmed:affiliation | Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA. | lld:pubmed |
| pubmed-article:20568761 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:20568761 | pubmed:publicationType | Research Support, N.I.H., Extramural | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:20568761 | lld:pubmed |
