| pubmed-article:20523949 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:20523949 | lifeskim:mentions | umls-concept:C0025552 | lld:lifeskim |
| pubmed-article:20523949 | lifeskim:mentions | umls-concept:C1704675 | lld:lifeskim |
| pubmed-article:20523949 | lifeskim:mentions | umls-concept:C0005036 | lld:lifeskim |
| pubmed-article:20523949 | lifeskim:mentions | umls-concept:C1704332 | lld:lifeskim |
| pubmed-article:20523949 | lifeskim:mentions | umls-concept:C0596801 | lld:lifeskim |
| pubmed-article:20523949 | lifeskim:mentions | umls-concept:C0678594 | lld:lifeskim |
| pubmed-article:20523949 | lifeskim:mentions | umls-concept:C0567415 | lld:lifeskim |
| pubmed-article:20523949 | lifeskim:mentions | umls-concept:C1720127 | lld:lifeskim |
| pubmed-article:20523949 | lifeskim:mentions | umls-concept:C0772162 | lld:lifeskim |
| pubmed-article:20523949 | lifeskim:mentions | umls-concept:C0127400 | lld:lifeskim |
| pubmed-article:20523949 | pubmed:issue | 27 | lld:pubmed |
| pubmed-article:20523949 | pubmed:dateCreated | 2010-7-2 | lld:pubmed |
| pubmed-article:20523949 | pubmed:abstractText | Aromatic pi-pi interaction in the presence of a metal atom has been investigated experimentally and theoretically with the model system of bis(eta(6)-benzene)chromium-benzene cluster (Cr(Bz)(2)-Bz) in which a free solvating benzene is non-covalently attached to the benzene moiety of Cr(Bz)(2). One-photon mass-analyzed threshold ionization (MATI) spectroscopy and first principles calculations are employed to identify the structure of Cr(Bz)(2)-Bz which adopts the parallel-displaced configuration. The decrease in ionization potential for Cr(Bz)(2)-Bz compared with Cr(Bz)(2), resulting from the increase of the cation-pi stabilization energy upon ionization, is consistent with the parallel-displaced structure of the cluster. Theoretical calculations give the detailed cluster structures with associated energetics, thus revealing the nature of pi-pi-metal or pi-pi-cation interactions at the molecular level. | lld:pubmed |
| pubmed-article:20523949 | pubmed:language | eng | lld:pubmed |
| pubmed-article:20523949 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20523949 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:20523949 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20523949 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20523949 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20523949 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20523949 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20523949 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20523949 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:20523949 | pubmed:month | Jul | lld:pubmed |
| pubmed-article:20523949 | pubmed:issn | 1463-9084 | lld:pubmed |
| pubmed-article:20523949 | pubmed:author | pubmed-author:KimSang KyuSK | lld:pubmed |
| pubmed-article:20523949 | pubmed:author | pubmed-author:KimKwang SKS | lld:pubmed |
| pubmed-article:20523949 | pubmed:author | pubmed-author:SinghN... | lld:pubmed |
| pubmed-article:20523949 | pubmed:author | pubmed-author:ChoiKyo-WonKW | lld:pubmed |
| pubmed-article:20523949 | pubmed:author | pubmed-author:BaekSun... | lld:pubmed |
| pubmed-article:20523949 | pubmed:author | pubmed-author:ChoiSunyoungS | lld:pubmed |
| pubmed-article:20523949 | pubmed:author | pubmed-author:KangTae... | lld:pubmed |
| pubmed-article:20523949 | pubmed:author | pubmed-author:HanSongheeS | lld:pubmed |
| pubmed-article:20523949 | pubmed:issnType | Electronic | lld:pubmed |
| pubmed-article:20523949 | pubmed:day | 21 | lld:pubmed |
| pubmed-article:20523949 | pubmed:volume | 12 | lld:pubmed |
| pubmed-article:20523949 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:20523949 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:20523949 | pubmed:pagination | 7648-53 | lld:pubmed |
| pubmed-article:20523949 | pubmed:meshHeading | pubmed-meshheading:20523949... | lld:pubmed |
| pubmed-article:20523949 | pubmed:meshHeading | pubmed-meshheading:20523949... | lld:pubmed |
| pubmed-article:20523949 | pubmed:meshHeading | pubmed-meshheading:20523949... | lld:pubmed |
| pubmed-article:20523949 | pubmed:meshHeading | pubmed-meshheading:20523949... | lld:pubmed |
| pubmed-article:20523949 | pubmed:meshHeading | pubmed-meshheading:20523949... | lld:pubmed |
| pubmed-article:20523949 | pubmed:meshHeading | pubmed-meshheading:20523949... | lld:pubmed |
| pubmed-article:20523949 | pubmed:meshHeading | pubmed-meshheading:20523949... | lld:pubmed |
| pubmed-article:20523949 | pubmed:meshHeading | pubmed-meshheading:20523949... | lld:pubmed |
| pubmed-article:20523949 | pubmed:meshHeading | pubmed-meshheading:20523949... | lld:pubmed |
| pubmed-article:20523949 | pubmed:year | 2010 | lld:pubmed |
| pubmed-article:20523949 | pubmed:articleTitle | Aromatic pi-pi interaction mediated by a metal atom: structure and ionization of the bis(eta(6)-benzene)chromium-benzene cluster. | lld:pubmed |
| pubmed-article:20523949 | pubmed:affiliation | Department of Chemistry, KAIST, Daejeon 305-701, Republic of Korea. | lld:pubmed |
| pubmed-article:20523949 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:20523949 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
