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pubmed-article:20430973rdf:typepubmed:Citationlld:pubmed
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pubmed-article:20430973pubmed:issue5982lld:pubmed
pubmed-article:20430973pubmed:dateCreated2010-5-28lld:pubmed
pubmed-article:20430973pubmed:abstractTextSelf-assembly is a powerful technique for the bottom-up construction of discrete, well-defined nanoscale structures. Large multicomponent systems (with more than 50 components) offer mechanistic insights into biological assembly but present daunting synthetic challenges. Here we report the self-assembly of giant M24L48 coordination spheres from 24 palladium ions (M) and 48 curved bridging ligands (L). The structure of this multicomponent system is highly sensitive to the geometry of the bent ligands. Even a slight change in the ligand bend angle critically switches the final structure observed across the entire ensemble of building blocks between M24L48 and M12L24 coordination spheres. The amplification of this small initial difference into an incommensurable difference in the resultant structures is a key mark of emergent behavior.lld:pubmed
pubmed-article:20430973pubmed:commentsCorrectionshttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:20430973pubmed:languageenglld:pubmed
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pubmed-article:20430973pubmed:statusPubMed-not-MEDLINElld:pubmed
pubmed-article:20430973pubmed:monthMaylld:pubmed
pubmed-article:20430973pubmed:issn1095-9203lld:pubmed
pubmed-article:20430973pubmed:authorpubmed-author:SokJ EJElld:pubmed
pubmed-article:20430973pubmed:authorpubmed-author:YamaguchiKent...lld:pubmed
pubmed-article:20430973pubmed:authorpubmed-author:IwasaJunjiJlld:pubmed
pubmed-article:20430973pubmed:authorpubmed-author:FujitaMakotoMlld:pubmed
pubmed-article:20430973pubmed:authorpubmed-author:OzekiTomojiTlld:pubmed
pubmed-article:20430973pubmed:authorpubmed-author:SeiYoshihisaYlld:pubmed
pubmed-article:20430973pubmed:authorpubmed-author:SunQing-FuQFlld:pubmed
pubmed-article:20430973pubmed:authorpubmed-author:IshidoYoshita...lld:pubmed
pubmed-article:20430973pubmed:authorpubmed-author:OgawaDaichiDlld:pubmed
pubmed-article:20430973pubmed:issnTypeElectroniclld:pubmed
pubmed-article:20430973pubmed:day28lld:pubmed
pubmed-article:20430973pubmed:volume328lld:pubmed
pubmed-article:20430973pubmed:ownerNLMlld:pubmed
pubmed-article:20430973pubmed:authorsCompleteYlld:pubmed
pubmed-article:20430973pubmed:pagination1144-7lld:pubmed
pubmed-article:20430973pubmed:year2010lld:pubmed
pubmed-article:20430973pubmed:articleTitleSelf-assembled M24L48 polyhedra and their sharp structural switch upon subtle ligand variation.lld:pubmed
pubmed-article:20430973pubmed:affiliationDepartment of Applied Chemistry, School of Engineering, The University of Tokyo and Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Corporation (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.lld:pubmed
pubmed-article:20430973pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:20430973pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed
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