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pubmed-article:19616780pubmed:dateCreated2009-8-3lld:pubmed
pubmed-article:19616780pubmed:abstractTextPoly(l-alanine)-grafted porous silica (Sil-Ala(22)) was prepared by polymerization of N-carboxyanhydride of l-alanine initiated by 3-aminopropylated silica. The retention behaviors of the column packed with Sil-Ala(22) were investigated by using alkylbenzenes and polycyclic aromatic hydrocarbons as injection samples in liquid chromatography. The Ala(22) phase was in a rigid beta-form structure and thus provided specific interaction sites, which were derived from the highly ordered carbonyl and methyl groups. These interaction sites bring unique molecular-shape discriminations: molecular-length and non-planarity selectivity, which are controllable by altering organic solvent used as a part of mobile phase.lld:pubmed
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pubmed-article:19616780pubmed:authorpubmed-author:NagaokaShojiSlld:pubmed
pubmed-article:19616780pubmed:authorpubmed-author:SakuraiToshih...lld:pubmed
pubmed-article:19616780pubmed:authorpubmed-author:IharaHirotaka...lld:pubmed
pubmed-article:19616780pubmed:authorpubmed-author:TakafujiMakot...lld:pubmed
pubmed-article:19616780pubmed:authorpubmed-author:ShundoAtsuomi...lld:pubmed
pubmed-article:19616780pubmed:authorpubmed-author:MallikAbul...lld:pubmed
pubmed-article:19616780pubmed:issnTypeElectroniclld:pubmed
pubmed-article:19616780pubmed:day21lld:pubmed
pubmed-article:19616780pubmed:volume1216lld:pubmed
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pubmed-article:19616780pubmed:pagination6170-6lld:pubmed
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pubmed-article:19616780pubmed:year2009lld:pubmed
pubmed-article:19616780pubmed:articleTitleControllable shape selectivity based on highly ordered carbonyl and methyl groups in simple beta-structural polypeptide on silica.lld:pubmed
pubmed-article:19616780pubmed:affiliationDepartment of Applied Chemistry and Biochemistry, Kumamoto University, Kumamoto 860-8555, Japan.lld:pubmed
pubmed-article:19616780pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:19616780pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed