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pubmed-article:19476323pubmed:dateCreated2010-5-28lld:pubmed
pubmed-article:19476323pubmed:abstractTextThe coordination-driven self-assembly of two metal-carbonyl-cluster-coordinated dipyridyl donors, (4-C(5)H(4)N)(2)C[triple bond]CCo(2)(CO)(6) (1) and (4-C(5)H(4)N)(2)C[triple bond]CMo(2)Cp(2)(CO)(4) (2), with a linear diplatinum(II) acceptor ligand was investigated. The structures of the resulting self-assembled polygons were found to be controlled by the steric bulk of the metal-carbonyl cluster adduct. The use of a sterically less imposing ligand 1 resulted in a pentagon-hexagon mixture, which was characterized by electrospray ionization time-of-flight mass spectroscopy. The exclusive formation of a [5 + 5] pentagon was achieved by the self-assembly of the bulkier molybdenum donor ligand 2 with a linear organoplatinum(II) acceptor ligand. Molecular force field modeling was used to study the structural details of the pentagonal and hexagonal architectures. The first Fe(3)-Co(6)-Pt(6) trimetal [3 + 3] hexagon was also synthesized via the combination of 1 with a 120 degrees ferrocenyldiplatinum(II) acceptor.lld:pubmed
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pubmed-article:19476323pubmed:authorpubmed-author:StangPeter...lld:pubmed
pubmed-article:19476323pubmed:authorpubmed-author:ZhaoLiangLlld:pubmed
pubmed-article:19476323pubmed:authorpubmed-author:WilliamsTaufi...lld:pubmed
pubmed-article:19476323pubmed:authorpubmed-author:GhoshKoushikKlld:pubmed
pubmed-article:19476323pubmed:authorpubmed-author:LyndonMatthew...lld:pubmed
pubmed-article:19476323pubmed:authorpubmed-author:ZhengYaorongYlld:pubmed
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pubmed-article:19476323pubmed:day6lld:pubmed
pubmed-article:19476323pubmed:volume48lld:pubmed
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pubmed-article:19476323pubmed:dateRevised2011-9-26lld:pubmed
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pubmed-article:19476323pubmed:year2009lld:pubmed
pubmed-article:19476323pubmed:articleTitleConstruction of coordination-driven self-assembled [5 + 5] pentagons using metal-carbonyl dipyridine ligands.lld:pubmed
pubmed-article:19476323pubmed:affiliationDepartment of Chemistry, University of Utah, 315 South 1400 East, Room 2020, Salt Lake City, Utah 84112, USA. liangz@chem.utah.edulld:pubmed
pubmed-article:19476323pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:19476323pubmed:publicationTypeResearch Support, N.I.H., Extramurallld:pubmed