pubmed-article:19476323 | rdf:type | pubmed:Citation | lld:pubmed |
pubmed-article:19476323 | lifeskim:mentions | umls-concept:C0023688 | lld:lifeskim |
pubmed-article:19476323 | lifeskim:mentions | umls-concept:C1527177 | lld:lifeskim |
pubmed-article:19476323 | lifeskim:mentions | umls-concept:C0441513 | lld:lifeskim |
pubmed-article:19476323 | lifeskim:mentions | umls-concept:C1709496 | lld:lifeskim |
pubmed-article:19476323 | pubmed:issue | 13 | lld:pubmed |
pubmed-article:19476323 | pubmed:dateCreated | 2010-5-28 | lld:pubmed |
pubmed-article:19476323 | pubmed:abstractText | The coordination-driven self-assembly of two metal-carbonyl-cluster-coordinated dipyridyl donors, (4-C(5)H(4)N)(2)C[triple bond]CCo(2)(CO)(6) (1) and (4-C(5)H(4)N)(2)C[triple bond]CMo(2)Cp(2)(CO)(4) (2), with a linear diplatinum(II) acceptor ligand was investigated. The structures of the resulting self-assembled polygons were found to be controlled by the steric bulk of the metal-carbonyl cluster adduct. The use of a sterically less imposing ligand 1 resulted in a pentagon-hexagon mixture, which was characterized by electrospray ionization time-of-flight mass spectroscopy. The exclusive formation of a [5 + 5] pentagon was achieved by the self-assembly of the bulkier molybdenum donor ligand 2 with a linear organoplatinum(II) acceptor ligand. Molecular force field modeling was used to study the structural details of the pentagonal and hexagonal architectures. The first Fe(3)-Co(6)-Pt(6) trimetal [3 + 3] hexagon was also synthesized via the combination of 1 with a 120 degrees ferrocenyldiplatinum(II) acceptor. | lld:pubmed |
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pubmed-article:19476323 | pubmed:language | eng | lld:pubmed |
pubmed-article:19476323 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19476323 | pubmed:citationSubset | IM | lld:pubmed |
pubmed-article:19476323 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19476323 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:19476323 | pubmed:status | MEDLINE | lld:pubmed |
pubmed-article:19476323 | pubmed:month | Jul | lld:pubmed |
pubmed-article:19476323 | pubmed:issn | 1520-510X | lld:pubmed |
pubmed-article:19476323 | pubmed:author | pubmed-author:StangPeter... | lld:pubmed |
pubmed-article:19476323 | pubmed:author | pubmed-author:ZhaoLiangL | lld:pubmed |
pubmed-article:19476323 | pubmed:author | pubmed-author:WilliamsTaufi... | lld:pubmed |
pubmed-article:19476323 | pubmed:author | pubmed-author:GhoshKoushikK | lld:pubmed |
pubmed-article:19476323 | pubmed:author | pubmed-author:LyndonMatthew... | lld:pubmed |
pubmed-article:19476323 | pubmed:author | pubmed-author:ZhengYaorongY | lld:pubmed |
pubmed-article:19476323 | pubmed:issnType | Electronic | lld:pubmed |
pubmed-article:19476323 | pubmed:day | 6 | lld:pubmed |
pubmed-article:19476323 | pubmed:volume | 48 | lld:pubmed |
pubmed-article:19476323 | pubmed:owner | NLM | lld:pubmed |
pubmed-article:19476323 | pubmed:authorsComplete | Y | lld:pubmed |
pubmed-article:19476323 | pubmed:pagination | 5590-2 | lld:pubmed |
pubmed-article:19476323 | pubmed:dateRevised | 2011-9-26 | lld:pubmed |
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pubmed-article:19476323 | pubmed:meshHeading | pubmed-meshheading:19476323... | lld:pubmed |
pubmed-article:19476323 | pubmed:year | 2009 | lld:pubmed |
pubmed-article:19476323 | pubmed:articleTitle | Construction of coordination-driven self-assembled [5 + 5] pentagons using metal-carbonyl dipyridine ligands. | lld:pubmed |
pubmed-article:19476323 | pubmed:affiliation | Department of Chemistry, University of Utah, 315 South 1400 East, Room 2020, Salt Lake City, Utah 84112, USA. liangz@chem.utah.edu | lld:pubmed |
pubmed-article:19476323 | pubmed:publicationType | Journal Article | lld:pubmed |
pubmed-article:19476323 | pubmed:publicationType | Research Support, N.I.H., Extramural | lld:pubmed |