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pubmed-article:19425027pubmed:abstractTextThe dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on eta(2) fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans-ligand binding explain the increased nucleophilicity of the resulting complexes 1-X.lld:pubmed
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pubmed-article:19425027pubmed:articleTitleStructural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex.lld:pubmed
pubmed-article:19425027pubmed:affiliationDepartment of Chemistry and Nano Science, and Center for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea.lld:pubmed
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