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pubmed-article:19243144pubmed:abstractTextThe direct observation of dynamic ligand exchange between Pt-N coordination-driven self-assembled supramolecular polygons (triangles and rectangles) has been achieved using stable (1)H/(2)D isotope labeling of the pyridyl donors and electrospray ionization mass spectrometry combined with NMR spectroscopy. Both the thermodynamic and kinetic aspects of such exchange processes have been established on the basis of quantitative mass spectral results. Further investigation has shown that the exchange is highly dependent on experimental conditions such as temperature, solvent, and the counteranions.lld:pubmed
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pubmed-article:19243144pubmed:authorpubmed-author:StangPeter...lld:pubmed
pubmed-article:19243144pubmed:authorpubmed-author:ZhengYao-Rong...lld:pubmed
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pubmed-article:19243144pubmed:dateRevised2011-9-26lld:pubmed
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pubmed-article:19243144pubmed:articleTitleDirect and quantitative characterization of dynamic ligand exchange between coordination-driven self-assembled supramolecular polygons.lld:pubmed
pubmed-article:19243144pubmed:affiliationDepartment of Chemistry, University of Utah, 315 South 1400 East, RM 2020, Salt Lake City, Utah 84112, USA. Zheng@chem.utah.edulld:pubmed
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