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pubmed-article:19183039pubmed:abstractTextMass uptake of water vapor was measured as a function of relative humidity for indomethacin glasses prepared using physical vapor deposition at different substrate temperatures. Highly stable glasses were produced on substrates at 265 K (0.84Tg) by depositing at 0.2 nm/s while samples similar to melt-cooled glasses were produced at 315 K and 5 nm/s. Samples deposited at 315 K absorb approximately the same amount of water as glasses prepared by supercooling the melt while stable glasses absorb a factor of 5 less water. Unexpectedly, the diffusion of water in the stable glass samples is 5-10 times faster than in the glass prepared by cooling the liquid.lld:pubmed
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pubmed-article:19183039pubmed:authorpubmed-author:KearnsKenneth...lld:pubmed
pubmed-article:19183039pubmed:authorpubmed-author:DawsonKevin...lld:pubmed
pubmed-article:19183039pubmed:authorpubmed-author:SacchettiMark...lld:pubmed
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pubmed-article:19183039pubmed:year2009lld:pubmed
pubmed-article:19183039pubmed:articleTitleHighly stable indomethacin glasses resist uptake of water vapor.lld:pubmed
pubmed-article:19183039pubmed:affiliationDepartment of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, USA.lld:pubmed
pubmed-article:19183039pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:19183039pubmed:publicationTypeResearch Support, U.S. Gov't, Non-P.H.S.lld:pubmed
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