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pubmed-article:19145620pubmed:abstractTextA copper-catalyzed transformation of peptidic thiol esters and boronic acids gives peptidyl ketones and takes place in DMF or DMF/H(2)O at room temperature in air (see scheme). This aerobic reaction only occurs at a thiol ester group capable of coordinating to Cu through its appendage on the sulfur center and is not hampered by racemization of the reactants or products.lld:pubmed
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pubmed-article:19145620pubmed:articleTitleA copper-catalyzed, pH-neutral construction of high-enantiopurity peptidyl ketones from peptidic s-acylthiosalicylamides in air at room temperature.lld:pubmed
pubmed-article:19145620pubmed:affiliationDepartment of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, GA 30322, USA. chemLL1@emory.edulld:pubmed
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