The rhombic dodecahedral Au nanocrystals enclosed by 12 {110} facets could be readily prepared without the use of any seeds, surfactants, or foreign metal ions but only with N,N-dimethylformamide as both reductant and solvent.
Department of Chemistry, Research Institute of Natural Science, Environmental Biotechnology National Core Research Center, Gyeongsang National University, Jinju 660-701, Korea.