| pubmed-article:19140782 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:19140782 | lifeskim:mentions | umls-concept:C0042306 | lld:lifeskim |
| pubmed-article:19140782 | lifeskim:mentions | umls-concept:C0030011 | lld:lifeskim |
| pubmed-article:19140782 | lifeskim:mentions | umls-concept:C1704241 | lld:lifeskim |
| pubmed-article:19140782 | lifeskim:mentions | umls-concept:C0301630 | lld:lifeskim |
| pubmed-article:19140782 | lifeskim:mentions | umls-concept:C1510824 | lld:lifeskim |
| pubmed-article:19140782 | lifeskim:mentions | umls-concept:C0332120 | lld:lifeskim |
| pubmed-article:19140782 | pubmed:issue | 2 | lld:pubmed |
| pubmed-article:19140782 | pubmed:dateCreated | 2009-1-14 | lld:pubmed |
| pubmed-article:19140782 | pubmed:abstractText | The reactivity of vanadium complexes bearing the ligand dipicolinic acid (H(2)dipic) with alcohols has been explored. Dipic vanadium complexes are able to catalyze the aerobic oxidative C-C bond cleavage of pinacol. Reaction under anaerobic conditions allowed for isolation of a V(III) mu-oxo dimer, supporting the involvement of V(III) in aerobic oxidation reactions. Stoichiometric oxidation of unactivated aliphatic alcohols has also been observed, with oxidation of cyclobutanol producing cyclobutanone in 93% yield. The absence of ring-opening products in this reaction provides further support for the involvement of V(III) intermediates. | lld:pubmed |
| pubmed-article:19140782 | pubmed:language | eng | lld:pubmed |
| pubmed-article:19140782 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19140782 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:19140782 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19140782 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19140782 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19140782 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19140782 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19140782 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:19140782 | pubmed:month | Jan | lld:pubmed |
| pubmed-article:19140782 | pubmed:issn | 1520-5126 | lld:pubmed |
| pubmed-article:19140782 | pubmed:author | pubmed-author:ScottBrian... | lld:pubmed |
| pubmed-article:19140782 | pubmed:author | pubmed-author:GordonJohn... | lld:pubmed |
| pubmed-article:19140782 | pubmed:author | pubmed-author:BakerR TomRT | lld:pubmed |
| pubmed-article:19140782 | pubmed:author | pubmed-author:SuttonAndrew... | lld:pubmed |
| pubmed-article:19140782 | pubmed:author | pubmed-author:ThornDavid... | lld:pubmed |
| pubmed-article:19140782 | pubmed:author | pubmed-author:HansonSusan... | lld:pubmed |
| pubmed-article:19140782 | pubmed:issnType | Electronic | lld:pubmed |
| pubmed-article:19140782 | pubmed:day | 21 | lld:pubmed |
| pubmed-article:19140782 | pubmed:volume | 131 | lld:pubmed |
| pubmed-article:19140782 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:19140782 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:19140782 | pubmed:pagination | 428-9 | lld:pubmed |
| pubmed-article:19140782 | pubmed:meshHeading | pubmed-meshheading:19140782... | lld:pubmed |
| pubmed-article:19140782 | pubmed:meshHeading | pubmed-meshheading:19140782... | lld:pubmed |
| pubmed-article:19140782 | pubmed:meshHeading | pubmed-meshheading:19140782... | lld:pubmed |
| pubmed-article:19140782 | pubmed:meshHeading | pubmed-meshheading:19140782... | lld:pubmed |
| pubmed-article:19140782 | pubmed:meshHeading | pubmed-meshheading:19140782... | lld:pubmed |
| pubmed-article:19140782 | pubmed:meshHeading | pubmed-meshheading:19140782... | lld:pubmed |
| pubmed-article:19140782 | pubmed:meshHeading | pubmed-meshheading:19140782... | lld:pubmed |
| pubmed-article:19140782 | pubmed:meshHeading | pubmed-meshheading:19140782... | lld:pubmed |
| pubmed-article:19140782 | pubmed:meshHeading | pubmed-meshheading:19140782... | lld:pubmed |
| pubmed-article:19140782 | pubmed:meshHeading | pubmed-meshheading:19140782... | lld:pubmed |
| pubmed-article:19140782 | pubmed:year | 2009 | lld:pubmed |
| pubmed-article:19140782 | pubmed:articleTitle | Aerobic oxidation of pinacol by vanadium(V) dipicolinate complexes: evidence for reduction to vanadium(III). | lld:pubmed |
| pubmed-article:19140782 | pubmed:affiliation | Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA. | lld:pubmed |
| pubmed-article:19140782 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:19140782 | pubmed:publicationType | Research Support, U.S. Gov't, Non-P.H.S. | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:19140782 | lld:pubmed |
