| pubmed-article:19123794 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:19123794 | lifeskim:mentions | umls-concept:C0443286 | lld:lifeskim |
| pubmed-article:19123794 | lifeskim:mentions | umls-concept:C0220781 | lld:lifeskim |
| pubmed-article:19123794 | lifeskim:mentions | umls-concept:C0439810 | lld:lifeskim |
| pubmed-article:19123794 | lifeskim:mentions | umls-concept:C1883254 | lld:lifeskim |
| pubmed-article:19123794 | lifeskim:mentions | umls-concept:C0185125 | lld:lifeskim |
| pubmed-article:19123794 | lifeskim:mentions | umls-concept:C0205099 | lld:lifeskim |
| pubmed-article:19123794 | lifeskim:mentions | umls-concept:C0449445 | lld:lifeskim |
| pubmed-article:19123794 | lifeskim:mentions | umls-concept:C1705294 | lld:lifeskim |
| pubmed-article:19123794 | lifeskim:mentions | umls-concept:C1259962 | lld:lifeskim |
| pubmed-article:19123794 | lifeskim:mentions | umls-concept:C1871593 | lld:lifeskim |
| pubmed-article:19123794 | pubmed:issue | 3 | lld:pubmed |
| pubmed-article:19123794 | pubmed:dateCreated | 2009-1-21 | lld:pubmed |
| pubmed-article:19123794 | pubmed:abstractText | A nontraditional approach to the enantiocontrolled construction of quaternary center-bearing heteroatom-bridged bicyclo[3.3.1]nonanes (homotropanes) is reported that is based on organometallic enantiomeric scaffolding. This strategy takes advantage of the unique reactivity profiles of TpMo(CO)(2)(5-oxo-eta(3)-pyranyl) and TpMo(CO)(2)(5-oxo-eta(3)-pyridinyl) scaffolds, and features a molybdenum-mediated semipinacol/1,5-"Michael-like" reaction sequence to establish the quaternary center and synthesize the bridged bicyclic structure. An asymmetric total synthesis of (-)-adaline highlights this methodology. | lld:pubmed |
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| pubmed-article:19123794 | pubmed:language | eng | lld:pubmed |
| pubmed-article:19123794 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19123794 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:19123794 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
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| pubmed-article:19123794 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:19123794 | pubmed:month | Jan | lld:pubmed |
| pubmed-article:19123794 | pubmed:issn | 1520-5126 | lld:pubmed |
| pubmed-article:19123794 | pubmed:author | pubmed-author:LiebeskindLan... | lld:pubmed |
| pubmed-article:19123794 | pubmed:author | pubmed-author:ZhangYongqian... | lld:pubmed |
| pubmed-article:19123794 | pubmed:author | pubmed-author:CoombsThomas... | lld:pubmed |
| pubmed-article:19123794 | pubmed:author | pubmed-author:Garnier-Ambla... | lld:pubmed |
| pubmed-article:19123794 | pubmed:issnType | Electronic | lld:pubmed |
| pubmed-article:19123794 | pubmed:day | 28 | lld:pubmed |
| pubmed-article:19123794 | pubmed:volume | 131 | lld:pubmed |
| pubmed-article:19123794 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:19123794 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:19123794 | pubmed:pagination | 876-7 | lld:pubmed |
| pubmed-article:19123794 | pubmed:dateRevised | 2011-9-26 | lld:pubmed |
| pubmed-article:19123794 | pubmed:meshHeading | pubmed-meshheading:19123794... | lld:pubmed |
| pubmed-article:19123794 | pubmed:meshHeading | pubmed-meshheading:19123794... | lld:pubmed |
| pubmed-article:19123794 | pubmed:meshHeading | pubmed-meshheading:19123794... | lld:pubmed |
| pubmed-article:19123794 | pubmed:meshHeading | pubmed-meshheading:19123794... | lld:pubmed |
| pubmed-article:19123794 | pubmed:meshHeading | pubmed-meshheading:19123794... | lld:pubmed |
| pubmed-article:19123794 | pubmed:meshHeading | pubmed-meshheading:19123794... | lld:pubmed |
| pubmed-article:19123794 | pubmed:meshHeading | pubmed-meshheading:19123794... | lld:pubmed |
| pubmed-article:19123794 | pubmed:year | 2009 | lld:pubmed |
| pubmed-article:19123794 | pubmed:articleTitle | Organometallic enantiomeric scaffolding. Sequential semipinacol/1,5-"Michael-like" reactions as a strategic approach to bridgehead-quaternary center aza[3.3.1]bicyclics: application to the total synthesis of (-)-adaline. | lld:pubmed |
| pubmed-article:19123794 | pubmed:affiliation | Sanford S. Atwood Chemistry Center, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, USA. | lld:pubmed |
| pubmed-article:19123794 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:19123794 | pubmed:publicationType | Research Support, N.I.H., Extramural | lld:pubmed |
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| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:19123794 | lld:pubmed |
