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pubmed-article:18958852pubmed:abstractTextA number of new synthetic methods for pi-conjugated oligoene and enyne compounds are described. Thus, diene and higher oligoene derivatives are selectively constructed by palladium-catalyzed arylation reactions of internal alkynes in the presence of arylboronic acids or alkenes as terminators. In contrast, the synthesis of various enyne derivatives is achieved effectively by homo- or cross dimerization of alkynes under rhodium catalysis.lld:pubmed
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pubmed-article:18958852pubmed:authorpubmed-author:SatohTetsuyaTlld:pubmed
pubmed-article:18958852pubmed:authorpubmed-author:MiuraMasahiro...lld:pubmed
pubmed-article:18958852pubmed:authorpubmed-author:TsurugiHayato...lld:pubmed
pubmed-article:18958852pubmed:copyrightInfoCopyright 2008 The Japan Chemical Journal Forum and Wiley Periodicals, Inc.lld:pubmed
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pubmed-article:18958852pubmed:year2008lld:pubmed
pubmed-article:18958852pubmed:articleTitleCatalytic synthesis of oligoene and enyne derivatives through carbometalation of internal alkynes.lld:pubmed
pubmed-article:18958852pubmed:affiliationDepartment of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. satoh@chem.eng.osaka-u.ac.jplld:pubmed
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