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pubmed-article:18715820pubmed:dateCreated2008-11-21lld:pubmed
pubmed-article:18715820pubmed:abstractTextN-methyl-alpha,beta,gamma,delta-tetraphenylporphine (NMTPPH) has been used to detect trace amount of zinc ions in ethanol-water solution by fluorescence spectroscopy. The fluorescent probe undergoes a fluorescent emission intensity enhancement upon binding to zinc ions in EtOH/H(2)O (1:1, v/v) solution. The fluorescence enhancement of NMTPPH is attributed to the 1:1 complex formation between NMTPPH and Zn(II) which has been utilized as the basis for the selective detection of Zn(II). The linear response range covers a concentration range of Zn(II) from 5.0x10(-7) to 1.0x10(-5)mol/L and the detection limit is 1.5x10(-7)mol/L. The fluorescent probe exhibits high selectivity over other common metal ions except for Cu(II).lld:pubmed
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pubmed-article:18715820pubmed:authorpubmed-author:Guo-LiShenSlld:pubmed
pubmed-article:18715820pubmed:authorpubmed-author:Ru-QinYuYlld:pubmed
pubmed-article:18715820pubmed:authorpubmed-author:ZhaoYanYlld:pubmed
pubmed-article:18715820pubmed:authorpubmed-author:ZhangXiao-Bin...lld:pubmed
pubmed-article:18715820pubmed:authorpubmed-author:LiChun-YanCYlld:pubmed
pubmed-article:18715820pubmed:authorpubmed-author:HanZhi-XiangZ...lld:pubmed
pubmed-article:18715820pubmed:authorpubmed-author:MaQiu-JuanQJlld:pubmed
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pubmed-article:18715820pubmed:volume71lld:pubmed
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pubmed-article:18715820pubmed:pagination1683-7lld:pubmed
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pubmed-article:18715820pubmed:year2009lld:pubmed
pubmed-article:18715820pubmed:articleTitleA fluorescent probe for zinc ions based on N-methyltetraphenylporphine with high selectivity.lld:pubmed
pubmed-article:18715820pubmed:affiliationState Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, PR China.lld:pubmed
pubmed-article:18715820pubmed:publicationTypeJournal Articlelld:pubmed
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pubmed-article:18715820pubmed:publicationTypeEvaluation Studieslld:pubmed