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pubmed-article:18540655pubmed:dateCreated2008-7-9lld:pubmed
pubmed-article:18540655pubmed:abstractTextCopper and titanium remain relatively plentiful in the earth's crust; hence, their use for large-scale solar energy conversion technologies is of significant interest. We describe fabrication of vertically oriented p-type Cu-Ti-O nanotube array films by anodization of copper rich (60% to 74%) Ti metal films cosputtered onto fluorine doped tin oxide (FTO) coated glass. Cu-Ti-O nanotube array films 1 mum thick exhibit external quantum efficiencies up to 11%, with a spectral photoresponse indicating that the complete visible spectrum, 380 to 885 nm, contributes significantly to the photocurrent generation. Water-splitting photoelectrochemical pn-junction diodes are fabricated using p-type Cu-Ti-O nanotube array films in combination with n-type TiO 2 nanotube array films. With the glass substrates oriented back-to-back, light is incident upon the UV absorbing n-TiO 2 side, with the visible light passing to the p-Cu-Ti-O side. In a manner analogous to photosynthesis, photocatalytic reactions are powered only by the incident light to generate fuel with oxygen evolved from the n-TiO 2 side of the diode and hydrogen from the p-Cu-Ti-O side. To date, we find under global AM 1.5 illumination that such photocorrosion-stable diodes generate a photocurrent of approximately 0.25 mA/cm (2), at a photoconversion efficiency of 0.30%.lld:pubmed
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pubmed-article:18540655pubmed:authorpubmed-author:SharmaSanjeev...lld:pubmed
pubmed-article:18540655pubmed:authorpubmed-author:GrimesCraig...lld:pubmed
pubmed-article:18540655pubmed:authorpubmed-author:ChoiKyoung-Sh...lld:pubmed
pubmed-article:18540655pubmed:authorpubmed-author:VargheseOomma...lld:pubmed
pubmed-article:18540655pubmed:authorpubmed-author:MorGopal KGKlld:pubmed
pubmed-article:18540655pubmed:authorpubmed-author:ShankarKarthi...lld:pubmed
pubmed-article:18540655pubmed:authorpubmed-author:LatempaThomas...lld:pubmed
pubmed-article:18540655pubmed:authorpubmed-author:WilkeRudeger...lld:pubmed
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pubmed-article:18540655pubmed:volume8lld:pubmed
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pubmed-article:18540655pubmed:pagination1906-11lld:pubmed
pubmed-article:18540655pubmed:dateRevised2008-10-30lld:pubmed
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pubmed-article:18540655pubmed:year2008lld:pubmed
pubmed-article:18540655pubmed:articleTitleP-type Cu--Ti--O nanotube arrays and their use in self-biased heterojunction photoelectrochemical diodes for hydrogen generation.lld:pubmed
pubmed-article:18540655pubmed:affiliationDepartment of Electrical Engineering, and Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802, USA.lld:pubmed
pubmed-article:18540655pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:18540655pubmed:publicationTypeResearch Support, U.S. Gov't, Non-P.H.S.lld:pubmed