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pubmed-article:18214pubmed:abstractTextCircularly polarized emission (CPE) and total emission (TE) spectra are reported for Eu3+ and Tb3+ complexes of L-aspartic acid (L-asp), L-serine (L-ser), L-threonine (L-thr) and L-histidine (L-his) in D2O solution under various pH conditions. Variations in TE and CPE intensities and in CPE splittings and sign patterns as functions of solution pH are correlated with lanthanide ion/ligand binding characteristics and with structural changes in the coordination environment of the metal ion. In the Eu3+/amino acid systems, the emission bands associated with the 5D0 leads to 7F1 and 7F2 Eu3+ transitions are monitored, and in the Tb3+/amino acid systems the 5D4 leads to 7F5 Tb3+ emission is examined.lld:pubmed
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pubmed-article:18214pubmed:issn0006-3061lld:pubmed
pubmed-article:18214pubmed:authorpubmed-author:RichardsonF...lld:pubmed
pubmed-article:18214pubmed:authorpubmed-author:BrittainH GHGlld:pubmed
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pubmed-article:18214pubmed:volume7lld:pubmed
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pubmed-article:18214pubmed:pagination233-43lld:pubmed
pubmed-article:18214pubmed:dateRevised2006-11-15lld:pubmed
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pubmed-article:18214pubmed:year1977lld:pubmed
pubmed-article:18214pubmed:articleTitleCircularly polarized emission studies on Tb3+ and Eu3+ complexes with potentially terdentate amino acids in aqueous solution.lld:pubmed
pubmed-article:18214pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:18214pubmed:publicationTypeResearch Support, U.S. Gov't, Non-P.H.S.lld:pubmed