| pubmed-article:18024189 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:18024189 | lifeskim:mentions | umls-concept:C0524637 | lld:lifeskim |
| pubmed-article:18024189 | lifeskim:mentions | umls-concept:C0009148 | lld:lifeskim |
| pubmed-article:18024189 | lifeskim:mentions | umls-concept:C0034407 | lld:lifeskim |
| pubmed-article:18024189 | lifeskim:mentions | umls-concept:C0220781 | lld:lifeskim |
| pubmed-article:18024189 | lifeskim:mentions | umls-concept:C1883254 | lld:lifeskim |
| pubmed-article:18024189 | lifeskim:mentions | umls-concept:C1705822 | lld:lifeskim |
| pubmed-article:18024189 | lifeskim:mentions | umls-concept:C0033727 | lld:lifeskim |
| pubmed-article:18024189 | lifeskim:mentions | umls-concept:C0348011 | lld:lifeskim |
| pubmed-article:18024189 | lifeskim:mentions | umls-concept:C1705938 | lld:lifeskim |
| pubmed-article:18024189 | lifeskim:mentions | umls-concept:C1527178 | lld:lifeskim |
| pubmed-article:18024189 | pubmed:issue | 2 | lld:pubmed |
| pubmed-article:18024189 | pubmed:dateCreated | 2008-6-9 | lld:pubmed |
| pubmed-article:18024189 | pubmed:abstractText | A new fluorescent chemosensor for sensing Co(II) using di(2-picolyl)amino (DPA) as a recognition group and quinazoline as a reporting group has been synthesized and characterized. The quinazoline derivative contains an intramolecular hydrogen bond, which would undergo excited-state intramolecular proton transfer (ESIPT) at illumination. The fluorescence quenching is attributed to cation-induced inhibition of ESIPT, which constitutes the basis for the determination of Co(II) with the prepared chemosensor. The fluorophore forms 1:1 cobalt(II) complex with the logarithm of apparent dissociation constant log K(a)=6.8. The analytical performance characteristics of the proposed Co(II)-sensitive sensor were investigated. The chemosensor exhibits a linear response toward Co(II) in the concentration range 3.2 x 10(-8) to 1.4 x 10(-6) M, with a working pH range from 7.0 to 9.5 and high selectivity. | lld:pubmed |
| pubmed-article:18024189 | pubmed:language | eng | lld:pubmed |
| pubmed-article:18024189 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:18024189 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:18024189 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:18024189 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:18024189 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:18024189 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:18024189 | pubmed:month | Jul | lld:pubmed |
| pubmed-article:18024189 | pubmed:issn | 1386-1425 | lld:pubmed |
| pubmed-article:18024189 | pubmed:author | pubmed-author:Guo-LiShenS | lld:pubmed |
| pubmed-article:18024189 | pubmed:author | pubmed-author:Ru-QinYuY | lld:pubmed |
| pubmed-article:18024189 | pubmed:author | pubmed-author:ZhangXiao-Bin... | lld:pubmed |
| pubmed-article:18024189 | pubmed:author | pubmed-author:LuoHong-YuanH... | lld:pubmed |
| pubmed-article:18024189 | pubmed:author | pubmed-author:HeChun-LianCL | lld:pubmed |
| pubmed-article:18024189 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:18024189 | pubmed:volume | 70 | lld:pubmed |
| pubmed-article:18024189 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:18024189 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:18024189 | pubmed:pagination | 337-42 | lld:pubmed |
| pubmed-article:18024189 | pubmed:meshHeading | pubmed-meshheading:18024189... | lld:pubmed |
| pubmed-article:18024189 | pubmed:meshHeading | pubmed-meshheading:18024189... | lld:pubmed |
| pubmed-article:18024189 | pubmed:meshHeading | pubmed-meshheading:18024189... | lld:pubmed |
| pubmed-article:18024189 | pubmed:meshHeading | pubmed-meshheading:18024189... | lld:pubmed |
| pubmed-article:18024189 | pubmed:meshHeading | pubmed-meshheading:18024189... | lld:pubmed |
| pubmed-article:18024189 | pubmed:meshHeading | pubmed-meshheading:18024189... | lld:pubmed |
| pubmed-article:18024189 | pubmed:year | 2008 | lld:pubmed |
| pubmed-article:18024189 | pubmed:articleTitle | Synthesis of dipicolylamino substituted quinazoline as chemosensor for cobalt(II) recognition based on excited-state intramolecular proton transfer. | lld:pubmed |
| pubmed-article:18024189 | pubmed:affiliation | State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry & Chemical Engineering, Hunan University, Changsha 410082, PR China. | lld:pubmed |
| pubmed-article:18024189 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:18024189 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
