| pubmed-article:17973381 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:17973381 | lifeskim:mentions | umls-concept:C1705165 | lld:lifeskim |
| pubmed-article:17973381 | lifeskim:mentions | umls-concept:C0678553 | lld:lifeskim |
| pubmed-article:17973381 | lifeskim:mentions | umls-concept:C2700061 | lld:lifeskim |
| pubmed-article:17973381 | pubmed:issue | 46 | lld:pubmed |
| pubmed-article:17973381 | pubmed:dateCreated | 2007-11-16 | lld:pubmed |
| pubmed-article:17973381 | pubmed:abstractText | The valence state change of BiNiO3 perovskite under pressure has been investigated by a powder neutron diffraction study and electronic-state calculations. At ambient pressure, BiNiO3 has the unusual charge distribution Bi(3+)(0.5)Bi(5+)(0.5)Ni(2+)O3 with ordering of Bi(3+) and Bi(5+)charges on the A sites of a highly distorted perovskite structure. High-pressure neutron diffraction measurements and bond valence sum calculations show that the pressure-induced melting of the charge disproportionated state leads to a simultaneous charge transfer from Ni to Bi, so that the high-pressure phase is metallic Bi(3+)Ni(3+)O3. This unprecedented charge transfer between A and B site cations coupled to electronic instabilities at both sites leads to a variety of ground states, and it is predicted that a Ni-charge disproportionated state should also be observable. | lld:pubmed |
| pubmed-article:17973381 | pubmed:language | eng | lld:pubmed |
| pubmed-article:17973381 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:17973381 | pubmed:status | PubMed-not-MEDLINE | lld:pubmed |
| pubmed-article:17973381 | pubmed:month | Nov | lld:pubmed |
| pubmed-article:17973381 | pubmed:issn | 0002-7863 | lld:pubmed |
| pubmed-article:17973381 | pubmed:author | pubmed-author:TsujimotoMasa... | lld:pubmed |
| pubmed-article:17973381 | pubmed:author | pubmed-author:RodgersJennif... | lld:pubmed |
| pubmed-article:17973381 | pubmed:author | pubmed-author:AzumaMasakiM | lld:pubmed |
| pubmed-article:17973381 | pubmed:author | pubmed-author:AttfieldJ... | lld:pubmed |
| pubmed-article:17973381 | pubmed:author | pubmed-author:TakanoMikioM | lld:pubmed |
| pubmed-article:17973381 | pubmed:author | pubmed-author:IsodaSeijiS | lld:pubmed |
| pubmed-article:17973381 | pubmed:author | pubmed-author:TuckerMatthew... | lld:pubmed |
| pubmed-article:17973381 | pubmed:author | pubmed-author:IshiwataShint... | lld:pubmed |
| pubmed-article:17973381 | pubmed:author | pubmed-author:ShimakawaYuic... | lld:pubmed |
| pubmed-article:17973381 | pubmed:author | pubmed-author:CarlssonSandr... | lld:pubmed |
| pubmed-article:17973381 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:17973381 | pubmed:day | 21 | lld:pubmed |
| pubmed-article:17973381 | pubmed:volume | 129 | lld:pubmed |
| pubmed-article:17973381 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:17973381 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:17973381 | pubmed:pagination | 14433-6 | lld:pubmed |
| pubmed-article:17973381 | pubmed:year | 2007 | lld:pubmed |
| pubmed-article:17973381 | pubmed:articleTitle | Pressure-induced intermetallic valence transition in BiNiO3. | lld:pubmed |
| pubmed-article:17973381 | pubmed:affiliation | Institute for Chemical Research, Kyoto University, Uji, Kyoto-fu 611-0011, Japan. masaki@scl.kyoto-u.ac.jp | lld:pubmed |
| pubmed-article:17973381 | pubmed:publicationType | Journal Article | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:17973381 | lld:pubmed |
