| pubmed-article:17957657 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:17957657 | lifeskim:mentions | umls-concept:C0520510 | lld:lifeskim |
| pubmed-article:17957657 | lifeskim:mentions | umls-concept:C0456387 | lld:lifeskim |
| pubmed-article:17957657 | lifeskim:mentions | umls-concept:C0024488 | lld:lifeskim |
| pubmed-article:17957657 | lifeskim:mentions | umls-concept:C0563532 | lld:lifeskim |
| pubmed-article:17957657 | lifeskim:mentions | umls-concept:C0205358 | lld:lifeskim |
| pubmed-article:17957657 | lifeskim:mentions | umls-concept:C0871161 | lld:lifeskim |
| pubmed-article:17957657 | pubmed:issue | 35 | lld:pubmed |
| pubmed-article:17957657 | pubmed:dateCreated | 2007-12-6 | lld:pubmed |
| pubmed-article:17957657 | pubmed:abstractText | A general approach toward amphiphilic systems bearing multimetallic clusters and their ability to form Langmuir-Blodgett films is presented. The synthetic strategy to stabilize these clusters involves the use of a ligand (HL) containing an N(2)O-donor set and long octadecanoic chains to obtain the carboxylate-supported [L(2)Cu(4)(mu(4)-O)(mu(2)-OAc)(4)]EtOH (1) and [L(2)Cu(4)(mu(4)-O)(mu(2)-OBz)(4)] (2) in which OAc(-) and OBz(-) represent acetate (1) and benzoate (2) co-ligands. These species were thoroughly characterized and had their structures solved by X-ray crystallography. We observed that the mu-oxo Cu(4) cluster is antiferromagnetically coupled and used broken-symmetry density functional theory (DFT) calculations to describe the main superexchange pathways of the tetracopper core. We also describe the amphiphilic properties of the ligand and the cluster-containing systems by means of area versus pressure isotherms and show that these cluster-bearing species can be transferred onto solid substrates yielding homogeneous Langmuir-Blodgett films, as characterized by atomic force microscopy and contact angle measurements. | lld:pubmed |
| pubmed-article:17957657 | pubmed:language | eng | lld:pubmed |
| pubmed-article:17957657 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:17957657 | pubmed:status | PubMed-not-MEDLINE | lld:pubmed |
| pubmed-article:17957657 | pubmed:issn | 0947-6539 | lld:pubmed |
| pubmed-article:17957657 | pubmed:author | pubmed-author:YeeGordon TGT | lld:pubmed |
| pubmed-article:17957657 | pubmed:author | pubmed-author:HeegMary... | lld:pubmed |
| pubmed-article:17957657 | pubmed:author | pubmed-author:HratchianHran... | lld:pubmed |
| pubmed-article:17957657 | pubmed:author | pubmed-author:NiSuolongS | lld:pubmed |
| pubmed-article:17957657 | pubmed:author | pubmed-author:ShakyaRajendr... | lld:pubmed |
| pubmed-article:17957657 | pubmed:author | pubmed-author:AllardMarcoM | lld:pubmed |
| pubmed-article:17957657 | pubmed:author | pubmed-author:da... | lld:pubmed |
| pubmed-article:17957657 | pubmed:author | pubmed-author:WuLiboL | lld:pubmed |
| pubmed-article:17957657 | pubmed:author | pubmed-author:HindoSarmad... | lld:pubmed |
| pubmed-article:17957657 | pubmed:author | pubmed-author:VeraniCláudio... | lld:pubmed |
| pubmed-article:17957657 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:17957657 | pubmed:volume | 13 | lld:pubmed |
| pubmed-article:17957657 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:17957657 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:17957657 | pubmed:pagination | 9948-56 | lld:pubmed |
| pubmed-article:17957657 | pubmed:dateRevised | 2009-8-4 | lld:pubmed |
| pubmed-article:17957657 | pubmed:year | 2007 | lld:pubmed |
| pubmed-article:17957657 | pubmed:articleTitle | Amphiphilic and magnetic properties of a new class of cluster-bearing [L2Cu4(mu4-O)(mu2-carboxylato)4] soft materials. | lld:pubmed |
| pubmed-article:17957657 | pubmed:affiliation | Department of Chemistry, Wayne State University, Detroit, MI 48202, USA. | lld:pubmed |
| pubmed-article:17957657 | pubmed:publicationType | Journal Article | lld:pubmed |
