pubmed-article:17727295 | rdf:type | pubmed:Citation | lld:pubmed |
pubmed-article:17727295 | lifeskim:mentions | umls-concept:C0443286 | lld:lifeskim |
pubmed-article:17727295 | lifeskim:mentions | umls-concept:C1704419 | lld:lifeskim |
pubmed-article:17727295 | lifeskim:mentions | umls-concept:C0332514 | lld:lifeskim |
pubmed-article:17727295 | pubmed:issue | 20 | lld:pubmed |
pubmed-article:17727295 | pubmed:dateCreated | 2007-9-21 | lld:pubmed |
pubmed-article:17727295 | pubmed:abstractText | C2-symmetric chiral bisformamides have been shown to catalyze the asymmetric one-pot, three-component Strecker reaction, which produced the alpha-amino nitriles in excellent yields (up to 99%) with good enantioselectivities (up to 86% ee). Optically pure products could be obtained after a single recrystallization. A possible transition state (TS 1) has been proposed to explain the origin of asymmetric inductivity and reactivity according to the geometry of catalyst 2a optimized at the B3LYP/6-31G(d) level and the absolute configuration of product 4a. | lld:pubmed |
pubmed-article:17727295 | pubmed:language | eng | lld:pubmed |
pubmed-article:17727295 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:17727295 | pubmed:citationSubset | IM | lld:pubmed |
pubmed-article:17727295 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:17727295 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:17727295 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:17727295 | pubmed:status | MEDLINE | lld:pubmed |
pubmed-article:17727295 | pubmed:month | Sep | lld:pubmed |
pubmed-article:17727295 | pubmed:issn | 0022-3263 | lld:pubmed |
pubmed-article:17727295 | pubmed:author | pubmed-author:FengXiaomingX | lld:pubmed |
pubmed-article:17727295 | pubmed:author | pubmed-author:LuChangC | lld:pubmed |
pubmed-article:17727295 | pubmed:author | pubmed-author:XiongYanY | lld:pubmed |
pubmed-article:17727295 | pubmed:author | pubmed-author:LiuXiaohuaX | lld:pubmed |
pubmed-article:17727295 | pubmed:author | pubmed-author:WenYuehongY | lld:pubmed |
pubmed-article:17727295 | pubmed:author | pubmed-author:HuangJinglunJ | lld:pubmed |
pubmed-article:17727295 | pubmed:issnType | Print | lld:pubmed |
pubmed-article:17727295 | pubmed:day | 28 | lld:pubmed |
pubmed-article:17727295 | pubmed:volume | 72 | lld:pubmed |
pubmed-article:17727295 | pubmed:owner | NLM | lld:pubmed |
pubmed-article:17727295 | pubmed:authorsComplete | Y | lld:pubmed |
pubmed-article:17727295 | pubmed:pagination | 7715-9 | lld:pubmed |
pubmed-article:17727295 | pubmed:meshHeading | pubmed-meshheading:17727295... | lld:pubmed |
pubmed-article:17727295 | pubmed:meshHeading | pubmed-meshheading:17727295... | lld:pubmed |
pubmed-article:17727295 | pubmed:meshHeading | pubmed-meshheading:17727295... | lld:pubmed |
pubmed-article:17727295 | pubmed:meshHeading | pubmed-meshheading:17727295... | lld:pubmed |
pubmed-article:17727295 | pubmed:year | 2007 | lld:pubmed |
pubmed-article:17727295 | pubmed:articleTitle | Chiral bisformamides as effective organocatalysts for the asymmetric one-pot, three-component strecker reaction. | lld:pubmed |
pubmed-article:17727295 | pubmed:affiliation | Key Laboratory of Green Chemistry & Technology (Sichuan University), Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China. | lld:pubmed |
pubmed-article:17727295 | pubmed:publicationType | Journal Article | lld:pubmed |
pubmed-article:17727295 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |