| pubmed-article:17284026 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:17284026 | lifeskim:mentions | umls-concept:C1705920 | lld:lifeskim |
| pubmed-article:17284026 | lifeskim:mentions | umls-concept:C0205332 | lld:lifeskim |
| pubmed-article:17284026 | lifeskim:mentions | umls-concept:C0033268 | lld:lifeskim |
| pubmed-article:17284026 | lifeskim:mentions | umls-concept:C0205250 | lld:lifeskim |
| pubmed-article:17284026 | pubmed:issue | 5 | lld:pubmed |
| pubmed-article:17284026 | pubmed:dateCreated | 2007-2-27 | lld:pubmed |
| pubmed-article:17284026 | pubmed:abstractText | Oxidation of 5,10,15,20-tetramesitylporphyrinatoiron(III) perchlorate, (TMP)FeIII(ClO4), with ferric perchlorate in acetonitrile gave a metastable species identified as (TMP)FeIV(ClO4)2 that decayed within seconds to the known isomeric species (TMP*+)FeIII(ClO4)2. Irradiation of the metastable species with 355 nm laser light gave a highly reactive transient that reacts with simple organic reductants (alkenes and arylalkanes) 5 orders of magnitude faster than known Compound I analogues, (TMP*+)FeIV(O)(X-). | lld:pubmed |
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| pubmed-article:17284026 | pubmed:language | eng | lld:pubmed |
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| pubmed-article:17284026 | pubmed:citationSubset | IM | lld:pubmed |
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| pubmed-article:17284026 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:17284026 | pubmed:month | Mar | lld:pubmed |
| pubmed-article:17284026 | pubmed:issn | 0020-1669 | lld:pubmed |
| pubmed-article:17284026 | pubmed:author | pubmed-author:NewcombMartin... | lld:pubmed |
| pubmed-article:17284026 | pubmed:author | pubmed-author:FungLeslie... | lld:pubmed |
| pubmed-article:17284026 | pubmed:author | pubmed-author:ZhangRuiR | lld:pubmed |
| pubmed-article:17284026 | pubmed:author | pubmed-author:PanZhengzheng... | lld:pubmed |
| pubmed-article:17284026 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:17284026 | pubmed:day | 5 | lld:pubmed |
| pubmed-article:17284026 | pubmed:volume | 46 | lld:pubmed |
| pubmed-article:17284026 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:17284026 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:17284026 | pubmed:pagination | 1517-9 | lld:pubmed |
| pubmed-article:17284026 | pubmed:dateRevised | 2011-9-26 | lld:pubmed |
| pubmed-article:17284026 | pubmed:meshHeading | pubmed-meshheading:17284026... | lld:pubmed |
| pubmed-article:17284026 | pubmed:meshHeading | pubmed-meshheading:17284026... | lld:pubmed |
| pubmed-article:17284026 | pubmed:meshHeading | pubmed-meshheading:17284026... | lld:pubmed |
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| pubmed-article:17284026 | pubmed:meshHeading | pubmed-meshheading:17284026... | lld:pubmed |
| pubmed-article:17284026 | pubmed:year | 2007 | lld:pubmed |
| pubmed-article:17284026 | pubmed:articleTitle | Photochemical production of a highly reactive porphyrin-iron-oxo species. | lld:pubmed |
| pubmed-article:17284026 | pubmed:affiliation | Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607, USA. | lld:pubmed |
| pubmed-article:17284026 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:17284026 | pubmed:publicationType | Research Support, N.I.H., Extramural | lld:pubmed |
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