A racemic [2]rotaxane, composed of an asymmetric rotor and an asymmetric axle, formed a diastereomer with an amino acid derivative, and showed an optical response for the chiral recognition.
Nanoarchitectonics Research Center, National Institute of Advanced Industrial Science and Technology, Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. n-kameta@aist.go.jp