| pubmed-article:16978701 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:16978701 | lifeskim:mentions | umls-concept:C1721071 | lld:lifeskim |
| pubmed-article:16978701 | pubmed:issue | 1 | lld:pubmed |
| pubmed-article:16978701 | pubmed:dateCreated | 2007-2-16 | lld:pubmed |
| pubmed-article:16978701 | pubmed:abstractText | Particle-loaded monoliths containing a polymethacrylamide backbone were prepared by suspending a silica-based chiral phase in the mixture of the monomers followed by in-situ polymerization in the capillary. As chiral selector l-4-hydroxyproline chemically bonded to 3 microm silica particles was used following the separation principle of ligand-exchange. Electrolytes containing Cu(II) ions were used. Amino acid enantiomers were separated by capillary-LC and CEC, whereby the latter showed the better resolution properties. For the chiral separation of alpha-hydroxy acids the EOF was reversed by copolymerizing diallyldimethylammonium chloride instead of vinylsulfonic acid as charge providing agent. Short columns of 6 cm were found to be sufficient in the case of CEC for baseline separations of amino acids with alpha values up to 5. | lld:pubmed |
| pubmed-article:16978701 | pubmed:language | eng | lld:pubmed |
| pubmed-article:16978701 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16978701 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:16978701 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16978701 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16978701 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16978701 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16978701 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16978701 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16978701 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16978701 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16978701 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16978701 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:16978701 | pubmed:month | Feb | lld:pubmed |
| pubmed-article:16978701 | pubmed:issn | 0165-022X | lld:pubmed |
| pubmed-article:16978701 | pubmed:author | pubmed-author:SchmidMartin... | lld:pubmed |
| pubmed-article:16978701 | pubmed:author | pubmed-author:GübitzGeraldG | lld:pubmed |
| pubmed-article:16978701 | pubmed:author | pubmed-author:KoidlJuliaJ | lld:pubmed |
| pubmed-article:16978701 | pubmed:author | pubmed-author:WankPamelaP | lld:pubmed |
| pubmed-article:16978701 | pubmed:author | pubmed-author:KarglGabriele... | lld:pubmed |
| pubmed-article:16978701 | pubmed:author | pubmed-author:ZöhrerHelgaH | lld:pubmed |
| pubmed-article:16978701 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:16978701 | pubmed:day | 23 | lld:pubmed |
| pubmed-article:16978701 | pubmed:volume | 70 | lld:pubmed |
| pubmed-article:16978701 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:16978701 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:16978701 | pubmed:pagination | 77-85 | lld:pubmed |
| pubmed-article:16978701 | pubmed:meshHeading | pubmed-meshheading:16978701... | lld:pubmed |
| pubmed-article:16978701 | pubmed:meshHeading | pubmed-meshheading:16978701... | lld:pubmed |
| pubmed-article:16978701 | pubmed:meshHeading | pubmed-meshheading:16978701... | lld:pubmed |
| pubmed-article:16978701 | pubmed:meshHeading | pubmed-meshheading:16978701... | lld:pubmed |
| pubmed-article:16978701 | pubmed:meshHeading | pubmed-meshheading:16978701... | lld:pubmed |
| pubmed-article:16978701 | pubmed:meshHeading | pubmed-meshheading:16978701... | lld:pubmed |
| pubmed-article:16978701 | pubmed:meshHeading | pubmed-meshheading:16978701... | lld:pubmed |
| pubmed-article:16978701 | pubmed:meshHeading | pubmed-meshheading:16978701... | lld:pubmed |
| pubmed-article:16978701 | pubmed:meshHeading | pubmed-meshheading:16978701... | lld:pubmed |
| pubmed-article:16978701 | pubmed:meshHeading | pubmed-meshheading:16978701... | lld:pubmed |
| pubmed-article:16978701 | pubmed:meshHeading | pubmed-meshheading:16978701... | lld:pubmed |
| pubmed-article:16978701 | pubmed:year | 2007 | lld:pubmed |
| pubmed-article:16978701 | pubmed:articleTitle | Enantioseparation by ligand-exchange using particle-loaded monoliths: capillary-LC versus capillary electrochromatography. | lld:pubmed |
| pubmed-article:16978701 | pubmed:affiliation | Institute of Pharmaceutical Sciences, Department of Pharmaceutical Chemistry, Karl-Franzens-University, Universitätsplatz 1, A-8010 Graz, Austria. martin.schmid@uni-graz.at | lld:pubmed |
| pubmed-article:16978701 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:16978701 | pubmed:publicationType | Comparative Study | lld:pubmed |
