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pubmed-article:16880915pubmed:dateCreated2006-8-1lld:pubmed
pubmed-article:16880915pubmed:abstractTextWe discuss the photochemistry and photodissociation dynamics of thymine as revealed by two-colour photofragment Doppler spectroscopy and by one-colour slice imaging. Thymine is optically excited into the pipi* state, known to deactivate quickly. The H atom photofragment spectra are dominated by two-photon excitation processes with subsequent statistical dissociation. This can be explained by absorption of a second photon from a long-lived dark state to a highly excited state that quickly deactivates to the electronic ground state. No evidence was found for an important role of the pisigma* excited state identified in adenine and many other heterocyclic molecules.lld:pubmed
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pubmed-article:16880915pubmed:dateRevised2006-11-15lld:pubmed
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pubmed-article:16880915pubmed:year2006lld:pubmed
pubmed-article:16880915pubmed:articleTitlePhotodissociation of thymine.lld:pubmed
pubmed-article:16880915pubmed:affiliationInstitute of Physical Chemistry, University of Würzburg, Am Hubland, D-97074, Würzburg.lld:pubmed
pubmed-article:16880915pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:16880915pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed
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