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pubmed-article:16858725pubmed:abstractTextCation-selective exhaustive injection (CSEI) is used as an on-line concentration method for the high-sensitivity analysis of illicit amphetamines using CE. Optimum conditions for the determination of amphetamine, methamphetamine and methylenedioxy-methamphetamine were investigated. Sodium dodecyl sulfate (25 mM) in 100 mM phosphate buffer (pH 2.9) with 20% methanol as organic additive was used as the background electrolyte for CE separation. The LOD, based on an S/N of 3:1, was about 0.01 microg/mL using normal capillary micellar electrokinetic chromatography, while by using CSEI in combination with micellar sweeping the sensitivity increased up to 1000-fold with the LOD lower than 50 pg/mL. The reproducibility of CSEI combined with micellar sweeping for analyzing amphetamines was satisfactory (relative standard deviation around 10% by using area ratios against an internal standard). This method is highly sensitive and can be used to analyze trace amount amphetamines in human hair.lld:pubmed
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pubmed-article:16858725pubmed:authorpubmed-author:WangMengMlld:pubmed
pubmed-article:16858725pubmed:authorpubmed-author:ChenDavid D...lld:pubmed
pubmed-article:16858725pubmed:authorpubmed-author:LiuHuweiHlld:pubmed
pubmed-article:16858725pubmed:authorpubmed-author:FangNingNlld:pubmed
pubmed-article:16858725pubmed:authorpubmed-author:MengPinjiaPlld:pubmed
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pubmed-article:16858725pubmed:year2006lld:pubmed
pubmed-article:16858725pubmed:articleTitleAnalysis of amphetamine, methamphetamine and methylenedioxy-methamphetamine by micellar capillary electrophoresis using cation-selective exhaustive injection.lld:pubmed
pubmed-article:16858725pubmed:affiliationDepartment of Forensic Science, China Peoples Public Security University, Beijing, China.lld:pubmed
pubmed-article:16858725pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:16858725pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed
pubmed-article:16858725pubmed:publicationTypeEvaluation Studieslld:pubmed