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pubmed-article:16837760pubmed:issue7lld:pubmed
pubmed-article:16837760pubmed:dateCreated2006-7-13lld:pubmed
pubmed-article:16837760pubmed:abstractTextThe effect of the central metal of columns packed with silica gels binding Ni(2+)- and Cu(2+)-phthalocyanine derivatives (Ni-and Cu-PCS(D)s) on the retention behavior of poly-aromatic-hydrocarbons (PAHs) thereof in a polar eluent was examined. The retention factors of PAHs on the Ni- and Cu-PCS(D)s in 80% methanol showed a good linear correlation. The Cu-PCS(D) column exhibited the pi-pi interactions for PAHs, while the Ni-PCS(D) column exhibited the pi-d interactions for PAHs in addition to the pi-pi interaction for PAHs. Further, an investigation of the retention behavior of anthracene derivatives having different substituents revealed that the Ni- and Cu-PCS(D) columns could recognize the differences of substituents only in a polar eluent.lld:pubmed
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pubmed-article:16837760pubmed:authorpubmed-author:HaginakaJunJlld:pubmed
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pubmed-article:16837760pubmed:volume22lld:pubmed
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pubmed-article:16837760pubmed:year2006lld:pubmed
pubmed-article:16837760pubmed:articleTitleHPLC retention behaviors of pi-electron rich compounds on Ni2+- and Cu2+-phthalocyanine derivatives bound to silica gels in polar eluents.lld:pubmed
pubmed-article:16837760pubmed:affiliationFaculty of Medicine, Kagawa University, Ikenobe, Miki-cho, Kagawa 761-0793, Japan.lld:pubmed
pubmed-article:16837760pubmed:publicationTypeJournal Articlelld:pubmed