Source:http://linkedlifedata.com/resource/pubmed/id/16711703
| Subject | Predicate | Object | Context |
|---|---|---|---|
| pubmed-article:16711703 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:16711703 | lifeskim:mentions | umls-concept:C1704241 | lld:lifeskim |
| pubmed-article:16711703 | lifeskim:mentions | umls-concept:C1883073 | lld:lifeskim |
| pubmed-article:16711703 | lifeskim:mentions | umls-concept:C0678594 | lld:lifeskim |
| pubmed-article:16711703 | lifeskim:mentions | umls-concept:C1880022 | lld:lifeskim |
| pubmed-article:16711703 | lifeskim:mentions | umls-concept:C0442821 | lld:lifeskim |
| pubmed-article:16711703 | pubmed:issue | 11 | lld:pubmed |
| pubmed-article:16711703 | pubmed:dateCreated | 2006-5-22 | lld:pubmed |
| pubmed-article:16711703 | pubmed:abstractText | The reactions of [Pt(NH3)2(NHCOtBu)2] and TlX3 (X = NO3-, Cl-, CF3CO2-) yielded dinuclear [{Pt(ONO2)(NH3)2(NHCOtBu)}Tl(ONO2)2(MeOH)] (2) and trinuclear complexes [{PtX(RNH2)2(NHCOtBu)2}2Tl]+ [X = NO3- (3), Cl- (5), CF3CO2- (6)], which were spectroscopically and structurally characterized. Strong Pt-Tl interaction in the complexes in solutions was indicated by both 195Pt and 205Tl NMR spectra, which exhibit very large one-bond spin-spin coupling constants between the heteronuclei (1J(PtTl)), 146.8 and 88.84 kHz for 2 and 3, respectively. Both the X-ray photoelectron spectra and the 195Pt chemical shifts reveal that the complexes have Pt centers whose oxidation states are close to that of Pt(III). Characterization of these complexes by X-ray diffraction analysis confirms that the Pt and Tl atoms are held together by very short Pt-Tl bonds and are supported by the bridging amidate ligands. The Pt-Tl bonds are shorter than 2.6 Angstrom, indicating a strong metal-metal attraction between these two metals. Compound 2 was found to activate the C-H bond of acetone to yield a platinum(IV) acetonate complex. This reactivity corresponds to the property of Pt(III) complexes. Density functional theory calculations were able to reproduce the large magnitude of the metal-metal spin-spin coupling constants. The couplings are sensitive to the computational model because of a delicate balance of metal 6s contributions in the frontier orbitals. The computational analysis reveals the role of the axial ligands in the magnitude of the coupling constants. | lld:pubmed |
| pubmed-article:16711703 | pubmed:language | eng | lld:pubmed |
| pubmed-article:16711703 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16711703 | pubmed:status | PubMed-not-MEDLINE | lld:pubmed |
| pubmed-article:16711703 | pubmed:month | May | lld:pubmed |
| pubmed-article:16711703 | pubmed:issn | 0020-1669 | lld:pubmed |
| pubmed-article:16711703 | pubmed:author | pubmed-author:ChenWanzhiW | lld:pubmed |
| pubmed-article:16711703 | pubmed:author | pubmed-author:ZieglerTomT | lld:pubmed |
| pubmed-article:16711703 | pubmed:author | pubmed-author:GlaserJuliusJ | lld:pubmed |
| pubmed-article:16711703 | pubmed:author | pubmed-author:MatsumotoKazu... | lld:pubmed |
| pubmed-article:16711703 | pubmed:author | pubmed-author:AutschbachJoc... | lld:pubmed |
| pubmed-article:16711703 | pubmed:author | pubmed-author:LiuFenghuiF | lld:pubmed |
| pubmed-article:16711703 | pubmed:author | pubmed-author:Le... | lld:pubmed |
| pubmed-article:16711703 | pubmed:author | pubmed-author:MaliarikMikha... | lld:pubmed |
| pubmed-article:16711703 | pubmed:issnType | lld:pubmed | |
| pubmed-article:16711703 | pubmed:day | 29 | lld:pubmed |
| pubmed-article:16711703 | pubmed:volume | 45 | lld:pubmed |
| pubmed-article:16711703 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:16711703 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:16711703 | pubmed:pagination | 4526-36 | lld:pubmed |
| pubmed-article:16711703 | pubmed:year | 2006 | lld:pubmed |
| pubmed-article:16711703 | pubmed:articleTitle | Spectral and structural characterization of amidate-bridged platinum-thallium complexes with strong metal-metal bonds. | lld:pubmed |
| pubmed-article:16711703 | pubmed:affiliation | Department of Chemistry, Zhejiang University, Hangzhou 310028, China. chenwzz@zju.edu.cn | lld:pubmed |
| pubmed-article:16711703 | pubmed:publicationType | Journal Article | lld:pubmed |