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pubmed-article:16662405pubmed:dateCreated2010-6-29lld:pubmed
pubmed-article:16662405pubmed:abstractTextl-Threonic acid is a natural constituent in leaves of Pelargonium crispum (L.) L'Hér (lemon geranium) and Rumex x acutus L. (sorrel). In both species, l-[(14)C]threonate is formed after feeding l-[U-(14)C]ascorbic acid to detached leaves. R. acutus leaves labeled with l-[4-(3)H]- or l-[6-(3)H]ascorbic acid produce l-[(3)H]threonate, in the first case internally labeled and in the second case confined to the hydroxymethyl group. These results are consistent with the formation of l-threonate from carbons three through six of l-ascorbic acid. Detached leaves of P. crispum oxidize l-[U-(14)C] threonate to l-[(14)C]tartrate whereas leaves of R. acutus produce negligible tartrate and the bulk of the (14)C appears in (14)CO(2), [(14)C]sucrose, and other products of carbohydrate metabolism. R. acutus leaves that are labeled with l-[U-(14)C]threonate release (14)CO(2) at linear rate until a limiting value of 25% of the total [U-(14)C]threonate is metabolized. A small quantity of [(14)C]glycerate is also produced which suggests a process involving decarboxylation of l-[U-(14)C]threonate.lld:pubmed
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pubmed-article:16662405pubmed:monthJunlld:pubmed
pubmed-article:16662405pubmed:issn0032-0889lld:pubmed
pubmed-article:16662405pubmed:authorpubmed-author:LoewusF AFAlld:pubmed
pubmed-article:16662405pubmed:authorpubmed-author:HelsperJ PJPlld:pubmed
pubmed-article:16662405pubmed:issnTypePrintlld:pubmed
pubmed-article:16662405pubmed:volume69lld:pubmed
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pubmed-article:16662405pubmed:authorsCompleteYlld:pubmed
pubmed-article:16662405pubmed:pagination1365-8lld:pubmed
pubmed-article:16662405pubmed:dateRevised2010-9-14lld:pubmed
pubmed-article:16662405pubmed:year1982lld:pubmed
pubmed-article:16662405pubmed:articleTitleMetabolism of l-Threonic Acid in Rumex x acutus L. and Pelargonium crispum (L.) L'Hér.lld:pubmed
pubmed-article:16662405pubmed:affiliationInstitute of Biological Chemistry, Washington State University, Pullman, Washington 99164.lld:pubmed
pubmed-article:16662405pubmed:publicationTypeJournal Articlelld:pubmed
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