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pubmed-article:16460054pubmed:abstractTextA novel energy-transfer system involving nonaggregated cationic porphyrins adsorbed on an anionic-type clay surface and the electron-transfer reaction that occurs after light harvesting are described. In the clay-porphyrin complexes, photochemical energy transfer from excited singlet zinc porphyrins to free-base porphyrins proceeds. The photochemical electron-transfer reaction from an electron donor in solution (hydroquinone) to the adsorbed porphyrin in the excited singlet state was also examined. Because the electron-transfer rate from the hydroquinone to the excited singlet free-base porphyrin is larger than that to the excited singlet zinc porphyrin, we conclude that the energy transfer accelerates the overall electron-transfer reaction.lld:pubmed
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pubmed-article:16460054pubmed:authorpubmed-author:TakagiShinsuk...lld:pubmed
pubmed-article:16460054pubmed:authorpubmed-author:InoueHaruoHlld:pubmed
pubmed-article:16460054pubmed:authorpubmed-author:EguchiMiharuMlld:pubmed
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pubmed-article:16460054pubmed:year2006lld:pubmed
pubmed-article:16460054pubmed:articleTitleLight-harvesting energy transfer and subsequent electron transfer of cationic porphyrin complexes on clay surfaces.lld:pubmed
pubmed-article:16460054pubmed:affiliationDepartment of Applied Chemistry, Faculty of Urban Environmental Sciences, Tokyo Metropolitan University, Minami-ohsawa 1-1, Hachiohji, Tokyo 192-0397, Japan.lld:pubmed
pubmed-article:16460054pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:16460054pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed