| pubmed-article:16432207 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:16432207 | lifeskim:mentions | umls-concept:C0038817 | lld:lifeskim |
| pubmed-article:16432207 | lifeskim:mentions | umls-concept:C0032863 | lld:lifeskim |
| pubmed-article:16432207 | lifeskim:mentions | umls-concept:C2004457 | lld:lifeskim |
| pubmed-article:16432207 | pubmed:issue | 5 | lld:pubmed |
| pubmed-article:16432207 | pubmed:dateCreated | 2006-2-1 | lld:pubmed |
| pubmed-article:16432207 | pubmed:abstractText | Light excitation powers the reversible shuttling movement of the ring component of a rotaxane between two stations located at a 1.3-nm distance on its dumbbell-shaped component. The photoinduced shuttling movement, which occurs in solution, is based on a "four-stroke" synchronized sequence of electronic and nuclear processes. At room temperature the deactivation time of the high-energy charge-transfer state obtained by light excitation is approximately 10 micros, and the time period required for the ring-displacement process is on the order of 100 micros. The rotaxane behaves as an autonomous linear motor and operates with a quantum efficiency up to approximately 12%. The investigated system is a unique example of an artificial linear nanomotor because it gathers together the following features: (i) it is powered by visible light (e.g., sunlight); (ii) it exhibits autonomous behavior, like motor proteins; (iii) it does not generate waste products; (iv) its operation can rely only on intramolecular processes, allowing in principle operation at the single-molecule level; (v) it can be driven at a frequency of 1 kHz; (vi) it works in mild environmental conditions (i.e., fluid solution at ambient temperature); and (vii) it is stable for at least 10(3) cycles. | lld:pubmed |
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| pubmed-article:16432207 | pubmed:language | eng | lld:pubmed |
| pubmed-article:16432207 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16432207 | pubmed:citationSubset | IM | lld:pubmed |
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| pubmed-article:16432207 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:16432207 | pubmed:month | Jan | lld:pubmed |
| pubmed-article:16432207 | pubmed:issn | 0027-8424 | lld:pubmed |
| pubmed-article:16432207 | pubmed:author | pubmed-author:StoddartJ... | lld:pubmed |
| pubmed-article:16432207 | pubmed:author | pubmed-author:BalzaniVincen... | lld:pubmed |
| pubmed-article:16432207 | pubmed:author | pubmed-author:Clemente-León... | lld:pubmed |
| pubmed-article:16432207 | pubmed:author | pubmed-author:CrediAlbertoA | lld:pubmed |
| pubmed-article:16432207 | pubmed:author | pubmed-author:VenturiMarghe... | lld:pubmed |
| pubmed-article:16432207 | pubmed:author | pubmed-author:FerrerBelénB | lld:pubmed |
| pubmed-article:16432207 | pubmed:author | pubmed-author:FloodAmar HAH | lld:pubmed |
| pubmed-article:16432207 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:16432207 | pubmed:day | 31 | lld:pubmed |
| pubmed-article:16432207 | pubmed:volume | 103 | lld:pubmed |
| pubmed-article:16432207 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:16432207 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:16432207 | pubmed:pagination | 1178-83 | lld:pubmed |
| pubmed-article:16432207 | pubmed:dateRevised | 2009-11-18 | lld:pubmed |
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| pubmed-article:16432207 | pubmed:year | 2006 | lld:pubmed |
| pubmed-article:16432207 | pubmed:articleTitle | Autonomous artificial nanomotor powered by sunlight. | lld:pubmed |
| pubmed-article:16432207 | pubmed:affiliation | Dipartimento di Chimica G. Ciamician, Università di Bologna, via Selmi 2, 40126 Bologna, Italy. vincenzo.balzani@unibo.it | lld:pubmed |
| pubmed-article:16432207 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:16432207 | pubmed:publicationType | Research Support, U.S. Gov't, Non-P.H.S. | lld:pubmed |
| pubmed-article:16432207 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
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